Selective reductions with stable indium trihydride reagents

被引：32

作者：

Abernethy, CD ^{[1
]}

Cole, ML ^{[1
]}

Davies, AJ ^{[1
]}

Jones, C ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 39期

基金：

英国工程与自然科学研究理事会;

关键词：

carbene; indium hydride; phosphine; selective reduction;

D O I：

10.1016/S0040-4039(00)01299-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbene and tertiary phosphine adducts of indane, [InH3{CN(Mes)C2H2N(Mes)}] and [InH3{P(C6H11)(3)}] (Mes = 2,4,6-trimethylphenyl), have been used to reduce unsaturated organic functionalities. The success and selectivity of these reductions relative to those carried out with lighter group 13 hydride complexes is discussed. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7567 / 7570

页数：4

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