Synthesis, Structure, Magnetic and Photocatalytic Properties of Nickel(II) Coordination Polymer Based on 1-(3,5-Dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic Acid Ligand

被引：4
作者：
Wang Lao-Bang [1 ]
Wang Ji-Jiang [1 ]
Yue Er-Lin [1 ]
Tang Long [1 ]
Wang Xiao [1 ]
Hou Xiang-Yang [1 ]
Zhang Yu-Qi [1 ]
机构：
[1] Yanan Univ, Coll Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan City Key Lab New Energy & New Funct Mat, Yanan 716000, Shannxi, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 37卷 / 04期
关键词：
coordination polymer; Ni(II); 1-(3,5-dicarboxybenzyl)-3,5-pyrazole dicarboxylic acid; magnetic property; photocatalytic properties; METAL-ORGANIC FRAMEWORKS; N-DONOR LIGANDS; CRYSTAL-STRUCTURE; 2,2'-OXYBIS(BENZOIC ACID); COMPLEXES; LUMINESCENCE; SORPTION; ZN(II);
D O I：
10.11862/CJIC.2021.089
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer {[Ni-2(L)(bib)(1.5)(H2O)(4)]center dot 3H(2)O}(n) (1) (H4L=1-(3,5-dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic acid, bib=1,4-bis(1-imidazolyl)benzene) was synthesized by hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analyses and thermogravimetric analysis. Complex 1 features a 3D network structure. The variable temperature magnetic susceptibility measurements reveal that there are antiferromagnetic interactions between the Ni(II) ions in complex 1. In addition, photocatalytic experiments indicated that complex 1 exhibited high photocatalytic activity up to 82.7% for the degradation of methylene blue pollutant.
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收藏
页码：744 / 750
页数：7
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