The role of peroxo complexes in the catalytic decomposition of H2O2 in the presence of Cu(II) hydroxides

被引：8

作者：

Elizarova, GL ^{[1
]}

Matvienko, LG ^{[1
]}

Ogorodnikova, OL ^{[1
]}

Parmon, VN ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

KINETICS AND CATALYSIS | 2000年 / 41卷 / 03期

关键词：

H202; Colloidal Solution; H202 Concentration; Catalytic Decomposition; Copper Hydroxide;

D O I：

10.1007/BF02755369

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic decomposition of hydrogen peroxide is studied in the presence of colloidal and silicagel-supported Cu(OH)(2). Copper peroxo complexes with different activities were identified. The reaction is molecular without radical formation. The mechanisms of H2O2 decomposition are discussed.

引用

页码：332 / 339

页数：8

共 50 条

[31] Efficient degradation of cefotaxime by a UV plus ferrihydrite/TiO2+H2O2 process: the important role of ferrihydrite in transferring photo-generated electrons from TiO2 to H2O2 [J].

Jiang, Qi ;

Zhu, Runliang ;

Zhu, Yanping ;

Chen, Qingze .

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2019, 94 (08) :2512-2521

[32] Growth of carbon nanofibers by the catalytic decomposition of methane over Ni-Cu/Al2O3 catalyst [J].

Popov, M., V ;

Bannov, A. G. .

MATERIALS TODAY-PROCEEDINGS, 2020, 31 :489-491

[33] Advances in Catalytic Decomposition of N2O by Noble Metal Catalysts [J].

Zhang, Yong ;

Tian, Zhigao ;

Huang, Lin ;

Fan, Honghong ;

Hou, Qiufei ;

Cui, Ping ;

Wang, Wanqiang .

CATALYSTS, 2023, 13 (06)

[34] Study on Catalytic Decomposition of N2O over Modified Zeolites [J].

Liu, Xingyong ;

Wei, Wei .

ADVANCES IN CHEMICAL ENGINEERING II, PTS 1-4, 2012, 550-553 :145-148

[35] Volatility of radioactive iodine under gamma irradiation: effects of H2O2 and NaOH on the decomposition rate of volatile molecular iodine dissolved in aqueous solutions [J].

Kim, TaeJun ;

Kim, Minsik ;

Jung, Sang-Hyuk ;

Yeon, Jei-Won .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2018, 316 (03) :1267-1272

[36] High Aspect Ratio Carbon Nanotube Membranes Decorated with Pt Nanoparticle Urchins for Micro Underwater Vehicle Propulsion via H2O2 Decomposition [J].

Marr, Kevin M. ;

Chen, Bolin ;

Mootz, Eric J. ;

Geder, Jason ;

Pruessner, Marius ;

Melde, Brian J. ;

Vanfleet, Richard R. ;

Medintz, Igor. L. ;

Iverson, Brian D. ;

Claussen, Jonathan C. .

ACS NANO, 2015, 9 (08) :7791-7803

[37] New insights into the influence of activated carbon surface oxygen groups on H2O2 decomposition and oxidation of pre-adsorbed volatile organic compounds [J].

Anfruns, Alba ;

Garcia-Suarez, Eduardo J. ;

Montes-Moran, Miguel A. ;

Gonzalez-Olmos, Rafael ;

Martin, Maria J. .

CARBON, 2014, 77 :89-98

[38] An efficient polyoxovanadate-catalyzed oxidative mineralization of phenols with 30% aqueous H2O2 [J].

Gao, Feixue ;

Hua, Ruimao .

CATALYSIS COMMUNICATIONS, 2006, 7 (06) :391-393

[39] Kinetics and efficiency of H2O2 activation by iron-containing minerals and aquifer materials [J].

Anh Le-Tuan Pham ;

Doyle, Fiona M. ;

Sedlak, David L. .

WATER RESEARCH, 2012, 46 (19) :6454-6462

[40] Adsorption and Decomposition of N2O on Cu/t-ZrO2(101) Surfaces [J].

Man Meiling ;

Gu Jiafang ;

Li Lu ;

Lin Huaxiang ;

Li Yi ;

Chen Wenkai .

CHINESE JOURNAL OF CATALYSIS, 2012, 33 (11) :1850-1856

← 1 2 3 4 5 →