The role of peroxo complexes in the catalytic decomposition of H2O2 in the presence of Cu(II) hydroxides

被引：8
|
作者：
Elizarova, GL [1 ]
Matvienko, LG [1 ]
Ogorodnikova, OL [1 ]
Parmon, VN [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
来源：
KINETICS AND CATALYSIS | 2000年 / 41卷 / 03期
关键词：
H202; Colloidal Solution; H202 Concentration; Catalytic Decomposition; Copper Hydroxide;
D O I：
10.1007/BF02755369
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic decomposition of hydrogen peroxide is studied in the presence of colloidal and silicagel-supported Cu(OH)(2). Copper peroxo complexes with different activities were identified. The reaction is molecular without radical formation. The mechanisms of H2O2 decomposition are discussed.
引用
收藏
页码：332 / 339
页数：8
相关论文
共 50 条
  • [1] The role of peroxo complexes in the catalytic decomposition of H2O2 in the presence of Cu(II) hydroxides
    G. L. Elizarova
    L. G. Matvienko
    O. L. Ogorodnikova
    V. N. Parmon
    Kinetics and Catalysis, 2000, 41 : 332 - 339
  • [2] CATALYTIC PROPERTIES OF MN(II) AND CO(II) CARBONATE COMPLEXES IN H2O2 DECOMPOSITION
    SYCHEV, AY
    ISAK, VG
    VANLAP, D
    ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (02): : 363 - 366
  • [3] Comparative study of the rate of decomposition of H2O2 and of atrazine by Fe(III)/H2O2, Cu(II)/H2O2, Fe(III)/Cu(II)/H2O2
    Gallard, H.
    De Laat, J.
    Legube, B.
    Revue des Sciences de l'Eau, 1999, 12 (04): : 713 - 728
  • [4] Effects of Cu(II) sources on catalytic activity of copper oxides for H2O2 decomposition
    Wang, WL
    Li, DS
    Qin, ZP
    Yue, KF
    Yang, WX
    CHINESE JOURNAL OF CATALYSIS, 2001, 22 (03) : 301 - 303
  • [5] CATALYTIC DECOMPOSITION OF H2O2 BY MN(II) COMPLEXES WITH ACETYLACETONE .1. NATURE AND ROLE OF INTERMEDIATE COMPOUNDS
    SYCHEV, AY
    ISAK, VG
    FYUNG, CTT
    ZHURNAL FIZICHESKOI KHIMII, 1984, 58 (09): : 2331 - 2332
  • [6] CATALYTIC ACTIVITY OF MN(II)-HISTIDINE COMPLEXES FOR THE OXIDATION OF INDIGO CARMINE IN THE PRESENCE OF H2O2
    NIEM, NV
    XUYEN, NV
    THOANG, HS
    REACTION KINETICS AND CATALYSIS LETTERS, 1987, 34 (02): : 317 - 322
  • [7] Catalytic activities of transition metal complexes on zeolites for the decomposition of H2O2
    Joshi, R
    Limye, SN
    OXIDATION COMMUNICATIONS, 1998, 21 (03): : 337 - 341
  • [8] CU2+ COMPLEXES OF POLYAMINO ACIDS IN AQUEOUS SOLUTION CATALYTIC ACTIVITY (H2O2 DECOMPOSITION) AND STRUCTURE
    SIGEL, H
    BLAUER, G
    HELVETICA CHIMICA ACTA, 1968, 51 (06) : 1246 - &
  • [9] CATALYTIC DECOMPOSITION OF H2O2 ON PLATINUM IN PRESENCE OF SATURATED ORGANIC-ACIDS
    DIBROVA, GY
    SEMENKINA, TM
    ELFIMOVA, GI
    BOGDANOVSKII, GA
    KINETICS AND CATALYSIS, 1978, 19 (02) : 406 - 409
  • [10] CATALYTIC DECOMPOSITION OF H2O2 ON PLATINUM IN PRESENCE OF SERIES OF ORGANIC-SUBSTANCES
    SEMIONKINA, TM
    ELFIMOVA, GI
    BOGDANOVSKII, GA
    VOVCHENKO, GD
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1977, 18 (03): : 365 - 367
12345