Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

被引：52

作者：

Liu, Xianchun ^{[1
]}

Xing, Yan ^{[1
]}

Wang, Xinlong ^{[1
]}

Xu, Hongbin ^{[2
]}

Liu, Xizheng ^{[1
]}

Shao, Kuizhan ^{[1
]}

Su, Zhongmin ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

[2] Minist Sci & Technol, China Sci & Technol Exchange Ctr, Beijing 100045, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 15期

关键词：

STRUCTURAL-CHARACTERIZATION; HYDROTHERMAL SYNTHESES; CRYSTAL-STRUCTURES; ZINC PHOSPHATE; ZEOLITE; ZINCOPHOSPHATE; POLYMER; CO(II);

D O I：

10.1039/b923028a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new chiral open-framework cobalt phosphite [C6N2H14][Co(HPO3)(2)] (1) with helical channels has been synthesized under solvothermal conditions in the presence of achiral organic amine. The circular dichroism (CD) spectrum indicates that the bulk crystals have optical activity. Magnetic measurements reveal that 1 is a weak ferromagnet.

引用

页码：2614 / 2616

页数：3

共 45 条

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