Synthesis and crystal structure of the coordination polymer of silver with 4,4′-bipyridylethylene [Ag(Bpe)](NO3)•3H2O

被引：3

作者：

Kokunov, Yu. V. ^{[1
]}

Gorbunova, Yu. E. ^{[1
]}

Khmelevskaya, L. V. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 51卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

Coordination Polymer; Bipyridyl; Silver Salt; Neighboring Chain; Supramolecular Framework;

D O I：

10.1134/S0036023606080079

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [Ag(Bpe)](NO3) center dot 3H(2)O (Bpe = 4,4'-bipyridylethylene, C12H10N2) is prepared and its crystal structure is determined. The crystals are triclinic: a = 9.073(2) angstrom, b = 10.074(2) angstrom, c = 10.391(2) angstrom, alpha = 61.18(3)degrees, beta = 72.11(3)degrees, gamma = 68.62(3)degrees, space group P (1) over bar, V = 764.7(3) angstrom(3), rho(calcd) = 1.764 g/cm(3), Z = 2. The structure is composed of polymeric catonic chains, [Ag(Bpe)](infinity)(+), NO3- counterions, and water molecules. The Ag+ ions are bound to the two N atomsof two crystallographically nonequivalent Bpe ligands and form a nearly linear coordination (Ag(1)-N(1), 2.219 angstrom; Ag(1)-N(2), 2.120(4) angstrom; N(1)Ag(1)N(2), 169.9(2)degrees).

引用

页码：1192 / 1197

页数：6

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