Electrochemical behavior of aluminium anode in super-gravity field and its application in copper removal from wastewater by electrocoagulation

Anodic passivation is a key problem to reduce the efficiency of electrocoagulation (EC) process. Super-gravity technology was introduced into EC process to enhance the treatment of heavy metal waste-water using pure aluminum electrode. The results showed that the removal ratio of Cu increased, and the cell voltage decreased with the increase of gravity coefficient, suggesting a promoting effect of super-gravity field on electrocoagulation process. Electrochemical behavior of aluminium anode in super-gravity field was analyzed by potentiodynamic polarization, cyclic voltammetry and electrochemical impedance spectroscopy. It was found that anodic polarization behavior of aluminium showed a typical characteristic of dissolution in super-gravity, rather than passivation in normal gravity. The type of anode dissolution changed from pitting corrosion to uniform corrosion in super-gravity field. The outer oxidized film of anode was thinning, and more Al3+ ions were released by anode dissolution, which was attributed to the super-gravity enhancement of the mass transfer process of Cl- ions. In addition, X-ray diffraction and Fourier transform infrared spectroscopy indicated that the flocs generated in super-gravity field had amorphous and looser Al-O framework structure. As a result, the efficiency of EC process was improved by super-gravity. (C) 2021 Elsevier Ltd. All rights reserved.