Chlorine free synthesis of organophosphorus compounds based on the functionalization of white phosphorus (P4)

被引：16

作者：

Abdreimova, RR

Akbayeva, DN

Polimbetova, GS

Caminade, AM

Majoral, JP

机构：

[1] Inst Organ Catalysis & Electrochem, Alma Ata 480100, Kazakhstan

[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2000年 / 156卷

关键词：

white phosphorus; phosphate; phosphite; catalysis;

D O I：

10.1080/10426500008045007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative alkoxylations of P-4 in toluene-alcohol solutions are studied. These reactions need oxygen, a catalyst (PdCl2, RuOHCl3, RuCl3) and a co-oxidant (CuCl2, NaNO2, FeCl3, 1,4-benzoquinone, NaBrO3). Trialkylphosphates (RO)(3)P(O) and dialkylphosphites (RO)(2)P(O)H are the major products of the reaction. Kinetic experiments concerning the rate of absorption of O-2 during these reactions are also reported.

引用

页码：239 / 254

页数：16