Chlorine free synthesis of organophosphorus compounds based on the functionalization of white phosphorus (P4)

被引：16
作者：
Abdreimova, RR
Akbayeva, DN
Polimbetova, GS
Caminade, AM
Majoral, JP
机构：
[1] Inst Organ Catalysis & Electrochem, Alma Ata 480100, Kazakhstan
[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2000年 / 156卷
关键词：
white phosphorus; phosphate; phosphite; catalysis;
D O I：
10.1080/10426500008045007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxidative alkoxylations of P-4 in toluene-alcohol solutions are studied. These reactions need oxygen, a catalyst (PdCl2, RuOHCl3, RuCl3) and a co-oxidant (CuCl2, NaNO2, FeCl3, 1,4-benzoquinone, NaBrO3). Trialkylphosphates (RO)(3)P(O) and dialkylphosphites (RO)(2)P(O)H are the major products of the reaction. Kinetic experiments concerning the rate of absorption of O-2 during these reactions are also reported.
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收藏
页码：239 / 254
页数：16
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