Four novel insecticidal sesquiterpene esters from Celastrus angulatus

被引：31

作者：

Ji, Zhiqing

Wu, Wenjun

Yang, Hua

Shi, Baojun

Wang, Mingan ^{[1
]}

机构：

[1] China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China

[2] NW Agr Univ, Dept Plant Protect, Yangling 712100, Shaanxi, Peoples R China

来源：

NATURAL PRODUCT RESEARCH | 2007年 / 21卷 / 04期

关键词：

Celastraceae; Celastrus angulatus; insecticide; beta-dihydroagarofuran sesquiterpene; celangulatin;

D O I：

10.1080/14786410701192967

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Four new insecticidal sesquiterpene polyol esters with a beta-dihydroagarofuran sesquiterpene skeleton, celangulatin C (1), celangulatin D (2), celangulatin E (3), and celangulatin F (4), and five known compounds 5-9 were isolated from the low-polar toluene extracts of the root bark of Celastrus angulatus by bioassay-guided fractionation. Their chemical structures were elucidated mainly by analyses of MS and NMR spectral data. Celangulatin C, E and F showed LD50 against Mythimna separata were 280.4, 1656.4 and 210.5 mu g m(-1), respectively.

引用

页码：334 / 342

页数：9

共 27 条

[21] Two new insecticidal sesquiterpene polyol esters from Celastrus angulatus [J].

Wang, M ;

Wu, WJ ;

Zhu, JN ;

Ji, ZQ ;

Zhou, WM .

NATURAL PRODUCT RESEARCH, 2006, 20 (07) :653-658

[22] Sesquiterpene polyol esters from Celastrus flagellaris [J].

Wang, MA ;

Chen, FH .

JOURNAL OF NATURAL PRODUCTS, 1997, 60 (06) :602-603

[23]

WANG MT, 1991, PHYTOCHEMISTRY, V30, P3931, DOI 10.1016/0031-9422(91)83438-Q

[24] Insecticidal sesquiterpene polyol esters from Celastrus angulatus [J].

Wu, WJ ;

Wang, MG ;

Zhou, WM ;

Zhu, JB ;

Ji, ZQ ;

Hu, ZN .

PHYTOCHEMISTRY, 2001, 58 (08) :1183-1187

[25] Five new insecticidal sesquiterpenoids from Celastrus angulatus [J].

Wu, WJ ;

Wang, MG ;

Zhu, JB ;

Zhou, WM ;

Hu, ZN ;

Ji, ZQ .

JOURNAL OF NATURAL PRODUCTS, 2001, 64 (03) :364-367

[26] CELANGULINS-II, CELANGULIN-III, AND CELANGULIN-IV - NEW INSECTICIDAL SESQUITERPENOIDS FROM CELASTRUS-ANGULATUS [J].

WU, WJ ;

TU, YQ ;

LIU, HX ;

ZHU, JB .

JOURNAL OF NATURAL PRODUCTS, 1992, 55 (09) :1294-1298

[27] Insecticidal sesquiterpene pyridine alkaloids from Euonymus species [J].

Zhu, JB ;

Wang, MG ;

Wu, WJ ;

Ji, ZQ ;

Hu, ZN .

PHYTOCHEMISTRY, 2002, 61 (06) :699-704

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