Four novel insecticidal sesquiterpene esters from Celastrus angulatus

被引：33
作者：
Ji, Zhiqing
Wu, Wenjun
Yang, Hua
Shi, Baojun
Wang, Mingan [1 ]
机构：
[1] China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China
[2] NW Agr Univ, Dept Plant Protect, Yangling 712100, Shaanxi, Peoples R China
来源：
NATURAL PRODUCT RESEARCH | 2007年 / 21卷 / 04期
关键词：
Celastraceae; Celastrus angulatus; insecticide; beta-dihydroagarofuran sesquiterpene; celangulatin;
D O I：
10.1080/14786410701192967
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Four new insecticidal sesquiterpene polyol esters with a beta-dihydroagarofuran sesquiterpene skeleton, celangulatin C (1), celangulatin D (2), celangulatin E (3), and celangulatin F (4), and five known compounds 5-9 were isolated from the low-polar toluene extracts of the root bark of Celastrus angulatus by bioassay-guided fractionation. Their chemical structures were elucidated mainly by analyses of MS and NMR spectral data. Celangulatin C, E and F showed LD50 against Mythimna separata were 280.4, 1656.4 and 210.5 mu g m(-1), respectively.
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页码：334 / 342
页数：9
相关论文
共 27 条
[1]  
BRUNING R, 1978, PHYTOCHEMISTRY, V17, P1821, DOI 10.1016/S0031-9422(00)88719-1
[2]   Antitumor agents.: 228.: Five new agarofurans, reissantins A-E, and cytotoxic principles from Reissantia buchananiii [J].
Chang, FR ;
Hayashi, K ;
Chen, IH ;
Liaw, CC ;
Bastow, KF ;
Nakanishi, Y ;
Nozaki, H ;
Cragg, GA ;
Wu, YC ;
Lee, KH .
JOURNAL OF NATURAL PRODUCTS, 2003, 66 (11) :1416-1420
[3]  
Chen F, 1999, CLIN CHEM, V45, P7
[4]   Immunosuppressive sesquiterpene alkaloids from Tripterygium wilfordii [J].
Duan, HQ ;
Takaishi, Y ;
Momota, H ;
Ohmoto, Y ;
Taki, T ;
Jia, YF ;
Li, D .
JOURNAL OF NATURAL PRODUCTS, 2001, 64 (05) :582-587
[5]   Novel sesquiterpene esters with alkaloid and monoterpene and related compounds from Tripterygium hypoglaucum:: A new class of potent anti-HIV agents [J].
Duan, HQ ;
Takaishi, Y ;
Bando, M ;
Kido, M ;
Imakura, Y ;
Lee, KH .
TETRAHEDRON LETTERS, 1999, 40 (15) :2969-2972
[6]   Sesquiterpene alkaloids from Tripterygium hypoglaucum and Tripterygium wilfordii:: A new class of potent anti-HIV agents [J].
Duan, HQ ;
Takaishi, Y ;
Imakura, Y ;
Jia, YF ;
Li, D ;
Cosentino, LM ;
Lee, KH .
JOURNAL OF NATURAL PRODUCTS, 2000, 63 (03) :357-361
[7]   Sesquiterpene alkaloids from Tripterygium hypoglaucum [J].
Duan, HQ ;
Kawazoe, K ;
Takaishi, Y .
PHYTOCHEMISTRY, 1997, 45 (03) :617-621
[8]   Sesquiterpene evoninate alkaloids from Tripterygium hypoglaucum [J].
Duan, HQ ;
Takaishi, Y .
PHYTOCHEMISTRY, 1999, 52 (08) :1735-1738
[9]  
JACOBSON M, 1958, AGR HDB USDA, V154, P44
[10]   Sesquiterpene esters from Celastrus orbiculatus and their structure-activity relationship on the modulation of multidrug resistance [J].
Kim, SE ;
Kim, HS ;
Hong, YS ;
Kim, YC ;
Lee, JJ .
JOURNAL OF NATURAL PRODUCTS, 1999, 62 (05) :697-700
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