Four novel insecticidal sesquiterpene esters from Celastrus angulatus

被引:31
作者
Ji, Zhiqing
Wu, Wenjun
Yang, Hua
Shi, Baojun
Wang, Mingan [1 ]
机构
[1] China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China
[2] NW Agr Univ, Dept Plant Protect, Yangling 712100, Shaanxi, Peoples R China
关键词
Celastraceae; Celastrus angulatus; insecticide; beta-dihydroagarofuran sesquiterpene; celangulatin;
D O I
10.1080/14786410701192967
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Four new insecticidal sesquiterpene polyol esters with a beta-dihydroagarofuran sesquiterpene skeleton, celangulatin C (1), celangulatin D (2), celangulatin E (3), and celangulatin F (4), and five known compounds 5-9 were isolated from the low-polar toluene extracts of the root bark of Celastrus angulatus by bioassay-guided fractionation. Their chemical structures were elucidated mainly by analyses of MS and NMR spectral data. Celangulatin C, E and F showed LD50 against Mythimna separata were 280.4, 1656.4 and 210.5 mu g m(-1), respectively.
引用
收藏
页码:334 / 342
页数:9
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