Syntheses, Structures, and Luminescence Properties of New Octahedral Cluster Complexes with Terminal Phenolate Ligands: [K(H2O)(CH3OH)3]2[Ph4P]2[M 6Cl12(O-C6H4-F)6] (M = Nb, Ta; Ph = phenyl)

被引：3

作者：

Xie, Tao ^{[1
]}

Friedrich, Aleksej ^{[2
]}

Lochbrunner, Stefan ^{[2
]}

Koeckerling, Martin ^{[1
]}

机构：

[1] Univ Rostock, Inst Chem, Solid State Inorgan Chem Grp, D-18059 Rostock, Germany

[2] Univ Rostock, Inst Phys, D-18051 Rostock, Germany

来源：

JOURNAL OF CLUSTER SCIENCE | 2015年 / 26卷 / 01期

关键词：

Niobium; Cluster; Phenolate ligand; X-ray diffraction; Luminescense; NIOBIUM; TANTALUM; COLOR; CORE;

D O I：

10.1007/s10876-014-0761-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster compounds [K(H2O)(CH3OH)(3)](2)[Ph4P](2)[M Cl-6(12)(para-O-C6H4-F)(6)] (M = Nb (1), Ta (2); Ph=phenyl) were obtained by the reaction of [Nb6Cl14(CH3OH)(4)]center dot 6aEuro...CH3OH with potassium p-fluorophenolat and tetraphenylphosphonium chloride. 1 and 2 were crystallized from CH3OH and characterized by X-ray single-crystal diffraction, IR-,H-1 NMR-,UV-Vis- and luminescence spectroscopy.

引用

页码：223 / 232

页数：10

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