La0.8Sr0.2Ga0.8Mg0.2O3 electrolytes prepared by vacuum cold spray under heated gas for improved performance of SOFCs

被引:10
作者
Wang, Li-Shuang [1 ]
Li, Cheng-Xin [1 ]
Ma, Kai [1 ]
Zhang, Shan-Lin [1 ]
Yang, Guan-Jun [1 ]
Li, Chang-Jiu [1 ]
机构
[1] Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
基金
国家重点研发计划;
关键词
Vacuum cold spray; Heated gas; LSGM; IT-SOFCs; OXIDE FUEL-CELLS; AEROSOL DEPOSITION METHOD; DOPED LAGAO3; SUBSTRATE HARDNESS; LSGM ELECTROLYTE; THICK-FILMS; COMPACTION; MECHANISM; CONDUCTIVITY; TEMPERATURE;
D O I
10.1016/j.ceramint.2018.04.220
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
High impact velocity of particles has found its common way into the vacuum cold spray (VCS), but heating gas may further intensify this function, resulting in significantly higher impact velocity. That's the original design idea to realize denser ceramic deposition at low temperature in this paper. In this study, a similar to 10 mu m thick La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) electrolyte layer for SOFCs is prepared by VCS under heated gas. The effects of gas temperature on the deposition behavior, mechanical and electrical properties of the coatings are investigated. Results show improvements in coating density, hardness and ionic conductivity at elevated temperature. Additionally, the output performance of cell with LSGM electrolytes deposited at gas temperature of 400 degrees C achieved an open circuit voltage of similar to 1.0 V and the maximum power density of 855 mW/cm(2) at 750 degrees C. Overall, these findings testify of the promising aspects of VCS method for preparing solid electrolyte films for IT-SOFCs.
引用
收藏
页码:13773 / 13781
页数:9
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