The synthesis, using microwave irradiation and characterization of novel, metal-free and metallophthalocyanines

被引：23

作者：

Acar, Irfan ^{[1
]}

Kantekin, Halit ^{[1
]}

Biyiklioglu, Zekeriya ^{[1
]}

机构：

[1] Karadeniz Tech Univ, Dept Chem, Fac Arts & Sci, TR-61080 Trabzon, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 02期

关键词：

Microwave; Phthalocyanine; Cyclotetramerization; Phthalonitrile; Nickel; Cobalt; ASSISTED SYNTHESIS; PHTHALOCYANINES;

D O I：

10.1016/j.jorganchem.2009.10.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of novel metal-free (4) and metallophthalocyanines (5, 6, 7 and 8) were prepared by cyclotetramerization of a novel 4-[2-(1-naphthyloxy)ethoxy]phthalonitrile (3). New substitute phthalocyanines showed the enhanced solubility in organic solvents. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-Vis and MS spectral data. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：151 / 155

页数：5

共 27 条

[1]

Bekaroglu O, 1996, APPL ORGANOMET CHEM, V10, P605, DOI 10.1002/(SICI)1099-0739(199610)10:8<605::AID-AOC527>3.0.CO

[2]

2-U

[3] Novel metallophthalocyanines bearing 3-(p-chlorophenyl)-5-p-tolyl-4H-1,2,4-triazole bulky substituents by microwave irradiation [J].

Bekircan, Olcay ;

Biyiklioglu, Zekeriya ;

Acar, Irfan ;

Bektas, Hakan ;

Kantekin, Halit .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (21-22) :3425-3429

[4] Synthesis and characterization of new metal-free and metallophthalocyanines containing spherical or cylindrical macrotricyclic moieties [J].

Bilgin, A ;

Ertem, B ;

Gök, Y .

POLYHEDRON, 2005, 24 (10) :1117-1124

[5] The synthesis and properties of new metal-free and metallophthalocyanines containing four diloop macrocyclic moieties [J].

Bilgin, Ahmet ;

Ertem, Beytullah ;

Gok, Yasar .

SUPRAMOLECULAR CHEMISTRY, 2006, 18 (04) :361-369

[6] Microwave-assisted synthesis and characterization of new soluble metal-free and metallophthalocyanines substituted with four tetrathiamacrocycles through oxy bridges [J].

Biyikhoglu, Zekeriya ;

Acar, Irfan ;

Kantekin, Halit .

INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (06) :630-632

[7] Synthesis, characterization and electrochemistry of a new organosoluble metal-free and metallophthalocyanines [J].

Biyikhoglu, Zekeriya ;

Guner, Ece Tugba ;

Topcu, Saim ;

Kantekin, Halit .

POLYHEDRON, 2008, 27 (06) :1707-1713

[8] A novel metal-free and metallophthalocyanines containing four 19-membered dithiadiazadioxa macrocycles by microwave irradiation: Synthesis and characterization [J].

Biyikhoglu, Zekeriya ;

Kantekin, Halit .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (03) :505-509

[9] The synthesis, using microwave irradiation and characterization of novel, organosoluble metal-free and metallophthalocyanines substituted with flexible crown ether moieties [J].

Biyiklioglu, Zekeriya ;

Kantekin, Halit .

DYES AND PIGMENTS, 2009, 80 (01) :17-21

[10] Microwave assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four pyridyl groups [J].

Biyiklioglu, Zekeriya ;

Kantekin, Halit .

TRANSITION METAL CHEMISTRY, 2007, 32 (07) :851-856

← 1 2 3 →