A correlation between crystal structure and catalytic activity in the solid solutions CdMoxW1-xO4

被引：16

作者：

Daturi, M ^{[1
]}

Savary, L ^{[1
]}

Costentin, G ^{[1
]}

Lavalley, JC ^{[1
]}

机构：

[1] ISMRA, Catalyse & Spectrochim Lab, F-14050 Caen, France

来源：

CATALYSIS TODAY | 2000年 / 61卷 / 1-4期

关键词：

crystal structure; CdMoxW1-xO4; catalytic activity; powder refinements; mild oxidation;

D O I：

10.1016/S0920-5861(00)00361-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Two CdMoxW1-xO4 solid solutions with the scheelite and the wolframite structures were synthesised via different techniques and their structures were determined from powder refinements. The limit of the reciprocal solubility of Mo in CdWO4 has been checked. Several compositions of the solid solutions have been tested in the catalytic mild oxidation of propane or propene and relations between the structures and the catalytic activity are proposed. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：231 / 236

页数：6

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