共 31 条
Efficiently enhancing the tracking and erosion resistance of silicone rubber by the synergism of fluorine-containing polyphenylsilsesquioxane and ureido-containing MQ silicone resin
被引:27
作者:

Wu, Tongyi
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South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China

Lai, Xuejun
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South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China

Liu, Fengjiao
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South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China

Li, Hongqiang
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h-index: 0
机构:
South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China

Zeng, Xingrong
论文数: 0 引用数: 0
h-index: 0
机构:
South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China
机构:
[1] South China Univ Technol, Coll Mat Sci & Engn, Key Lab Guangdong Prov High Property & Funct Poly, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Silicone rubber;
Tracking and erosion resistance;
Hydrophobicity;
Fluorine-containing polyphenylsilsesquioxane;
Ureido-containing MQ silicone resin;
CONTAINING SILANE;
THERMAL-CONDUCTIVITY;
MECHANISM;
PLATINUM;
DEGRADATION;
INSULATORS;
COATINGS;
ATH;
D O I:
10.1016/j.apsusc.2018.08.021
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
It is of great interest and challenge to simultaneously improve the anti-pollution and tracking resistance of silicone rubber for its application in outdoor high voltage insulation. In this work, we proposed an efficient approach to address this issue by incorporating fluorine-containing polyphenylsilsesquioxane (F-PPSS) and ureido-containing MQ silicone resin (U-MQ) into addition-cure liquid silicone rubber (ALSR). F-PPSS/U-MQ significantly improved the tracking resistance and hydrophobicity of ALSR. By adding 2 phr F-PPSS and 1 phr U-MQ, ALSR passed the 1A 4.5 level inclined plane WA with merely 0.2% eroded mass, and had a water contact angle as high as 121 degrees. The synergism of F-PPSS and U-MQ on suppressing the ALSR degradation was further revealed and demonstrated. Our findings exhibited great potentials for fabricating silicone rubber with prominent tracking and erosion resistance by the combination of prevention and inhibition of tracking damage, endowing it with excellent long-term stable service performance.
引用
收藏
页码:483 / 491
页数:9
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