Sol-gel synthesis of chromium orthophosphate

被引:0
|
作者
Vykhodtseva, KI [1 ]
Tarasova, DV [1 ]
Yakovleva, TN [1 ]
Soderzhinova, MM [1 ]
Dulina, RS [1 ]
机构
[1] LY Karpov Phys Chem Res Inst, Moscow 103064, Russia
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中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Chromium orthophosphate was prepared by the soi-gel method from chromium(VI) oxide, orthophosphoric acid, and glycerol, using water as a solvent. Synthesis conditions (solution concentration, glycerol-to-chromium molar ratio, temperature) determine the gelation time but have little effect on the resultant chromium orthophosphate. The presence of excess glycerol favors formation of amorphous dehydrated chromium orthophosphate with a high specific surface area.
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页码:491 / 495
页数:5
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