Multimode Diffusion of Ring Polymer Molecules Revealed by a Single-Molecule Study

被引:72
作者
Habuchi, Satoshi [1 ]
Satoh, Norihiro [1 ]
Yamamoto, Takuya [1 ]
Tezuka, Yasuyuki [1 ]
Vacha, Martin [1 ]
机构
[1] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan
基金
日本学术振兴会;
关键词
diffusion; polymers; single-molecule studies; topological polymers; COVALENT FIXATION; PHASE-TRANSITION; DNA-MOLECULES; DYNAMICS; COEFFICIENTS; ARCHITECTURE; TELECHELICS; TOPOLOGIES; DEPENDENCE; REPTATION;
D O I
10.1002/anie.200904394
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) (Figure Presented) Molecular twister: A single-molecule study in a semi-dilute regime on a synthetic ring polymer containing a fluorescent perylene diimide unit (see picture, orange) reveals the heterogeneity of the system. The investigation indicates partial threading of the cyclic chains with the linear polymer matrix. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA.
引用
收藏
页码:1418 / 1421
页数:4
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