Chemical vapour transport of intermetallic phases, II:: The system Fe-Si

被引:0
作者
Bosholm, O
Oppermann, H
Däbritz, S
机构
[1] TU Dresden, Inst Anorgan Chem, D-01069 Dresden, Germany
[2] TU Dresden, Inst Oberflachen & Mikrostrukturphys, D-01069 Dresden, Germany
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2000年 / 55卷 / 07期
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Five phases exist in the system Fe-Si: Fe3Si, Fe2Si, Fe5Si3, FeSi, alpha- and beta-FeSi2. All phases could be prepared by chemical transport with iodine as transport agent in the temperature range between T-1 (700 degrees C) and T-2 (1030 degrees C). In a attempted systematic clarification of the chemical transport reactions of all phases in the system, the effective transport equilibria were determined. Thermodynamic calculations show satisfactory agreement between calculation and experiment.
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页码:614 / 626
页数:13
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