Gold Nanoclusters as a Catalyst for Intramolecular Addition of Primary Amines to Unactivated Alkenes under Aerobic Conditions

被引：37
作者：
Kitahara, Hiroaki [1 ]
Sakurai, Hidehiro [1 ,2 ,3 ]
机构：
[1] Grad Univ Adv Studies, Sch Phys Sci, Okazaki, Aichi 4448787, Japan
[2] Inst Mol Sci, Res Ctr Mol Scale Nanosci, Okazaki, Aichi 4448787, Japan
[3] Japan Sci & Technol Agcy, PRESTO, Tokyo 1020075, Japan
来源：
CHEMISTRY LETTERS | 2010年 / 39卷 / 01期
关键词：
INTERMOLECULAR HYDROAMINATION; REDUCTIVE AMINATION; OXIDATION; OLEFINS; WATER; COMPLEXES; NANOPARTICLES; CARBOXAMIDES; EFFICIENT; ALCOHOL;
D O I：
10.1246/cl.2010.46
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gold nanoclusters stabilized by the poly(N-vinyl-2-pyrrolidone) hydrophilic polymer (Au:PVP) catalyzed the intramolecular cycloaddition of primary amines to unactivated alkenes in the presence of formic acid derivatives. The reaction proceeded under neutral to slightly acidic conditions in air.
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收藏
页码：46 / 48
页数：3
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