Organotellurium catalysis-enabled utilization of molecular oxygen as oxidant for oxidative deoximation reactions under solvent-free conditions

被引：60
作者：
Deng, Xin [1 ]
Cao, Hongen [1 ,3 ]
Chen, Chao [1 ]
Zhou, Hongwei [2 ]
Yu, Lei [1 ]
机构：
[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
[2] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China
[3] Guizhou Univ, Res & Dev Ctr Fine Chem, Key Lab Green Pesticide & Agr Bioengn, Minist Educ,State Key Lab Breeding Base Green Pes, Guiyang 550025, Guizhou, Peoples R China
来源：
SCIENCE BULLETIN | 2019年 / 64卷 / 17期
关键词：
Chalcogen; Organotellurium catalysis; Aerobic oxidation; Deoximation; Free radical; Tellurium; ORGANOSELENIUM COMPOUNDS; FUNCTIONALIZATION; OLEFINS; ACCESS;
D O I：
10.1016/j.scib.2019.07.007
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Catalyzed by commercially available (PhTe)(2), molecular oxygen could be utilized as the mild, cheap and safe oxidant for oxidative deoximation reactions under solvent-free conditions. As the first report on organotellurium-catalyzed deoximation reaction, this work not only provides an efficient deoximation method, but also discloses new features of tellurium catalyst different from those of the organoselenium catalysts. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
引用
收藏
页码：1280 / 1284
页数：5
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