Synthesis, Photopolymerization, and Adhesive Properties of New Bisphosphonic Acid Monomers for Dental Application

被引：38

作者：

Catel, Yohann ^{[1
]}

Degrange, Michel ^{[2
]}

Le Pluart, Loic ^{[1
]}

Madec, Pierre-Jean ^{[1
]}

Pham, Thi-Nhan ^{[1
]}

Chen, Fei ^{[3
]}

Cook, Wayne D. ^{[3
]}

机构：

[1] Univ Caen Basse Normandie, CNRS, ENSICAEN, Lab Chim Mol & Thioorgan, F-14050 Caen, France

[2] Univ Paris 05, Unite Rech Biomat & Interfaces, Fac Chirurg Dentaire, F-92120 Montrouge, France

[3] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 20期

关键词：

acrylamide; adhesives; bisphosphonic acid; dental polymers; photopolymerization; synthesis; HYDROLYTIC STABILITY; DEGRADATION; POLYMERIZATION; CONVERSION; KINETICS; BREAST;

D O I：

10.1002/pola.23575

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Four new monomers, 3-(N-methylacrylamido)propylidenebisphosphonic acid, 3-(N-propyl-acrylamido)propylidenebisphosphonic acid, 3-(N-hexylacrylamido)propylidenebisphosphonic acid, and 3-(N-octylacrylamido)propylidenebisphosphonic acid, have been synthesized in good yields and fully characterized by H-1, C-13, P-31 NMR, and HRMS. The copolymerization of these monomers with N,N'-diethyl-1,3-bis(acrylamido)propane (DEBAAP) has been investigated with differential scanning calorimetry. These mixtures show a higher reactivity than DEBAAP. New self-etch dental primers, based on these acrylamide monomers, have been formulated. Dentin shear bond strength measurements have shown that primers based on these bisphosphonic acids assure a strong bond between the tooth substance and a dental composite. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5258-5271, 2009

引用

页码：5258 / 5271

页数：14

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