Baeyer-Villiger oxidation of ketones with hydrogen peroxide catalyzed by Sn-aniline complex

被引：11

作者：

Zhang, Qing Hua ^{[1
]}

Wang, Shou Feng ^{[1
]}

Lei, Zi Qiang ^{[1
]}

机构：

[1] NW Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Lanzhou 730070, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2007年 / 18卷 / 01期

关键词：

Baeyer-Villiger oxidation; Sn-aniline complex; ketone oxidation; hydrogen peroxide;

D O I：

10.1016/j.cclet.2006.11.036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sn-aniline complex was prepared by a simple procedure. Cyclic and acyclic ketones were oxidized into lactones or esters with very high selectivity and yield with 30% hydrogen peroxide in the presence of Sn-aniline complex. (c) 2006 Zi Qiang Lei. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：4 / 6

页数：3

共 8 条

[1] Lewis acidic Sn(IV) centers - grafted onto MCM-41 - as catalytic sites for the Baeyer-Villiger oxidation with hydrogen peroxide [J].

Corma, A ;

Navarro, MT ;

Renz, M .

JOURNAL OF CATALYSIS, 2003, 219 (01) :242-246

[2] Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer-Villiger oxidations [J].

Corma, A ;

Nemeth, LT ;

Renz, M ;

Valencia, S .

NATURE, 2001, 412 (6845) :423-425

[3] REACTIONS OF PERACIDS .4. THE REACTION OF CYCLOHEXYLPHENYL KETONE WITH PERBENZOIC ACID [J].

FRIESS, SL ;

FARNHAM, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (12) :5518-5521

[4]

Krow G.R., 1993, ORGANIC REACTIONS, V43, P251, DOI DOI 10.1002/0471264180.OR043.03

[5]

Krow G. R, 1991, COMPREHENSIVE ORGANI, V7

[6] Baeyer-Villiger oxidation of ketones with hydrogen peroxide catalyzed by Sn-palygorskite [J].

Lei, ZQ ;

Zhang, QH ;

Luo, JJ ;

He, XY .

TETRAHEDRON LETTERS, 2005, 46 (20) :3505-3508

[7] Enzyme-catalysed Baeyer-Villiger oxidations [J].

Roberts, SM ;

Wan, PWH .

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 1998, 4 (03) :111-136

[8] OXIDATIVE RING ENLARGEMENT OF CYCLIC KETONES BY PEROXYTRIFLUOROACETIC ACID [J].

SAGER, WF ;

DUCKWORTH, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (01) :188-190

← 1 →