Spin crossover in a heptanuclear mixed-valence iron complex

被引：42

作者：

Boca, Roman ^{[1
,2
]}

Salitros, Ivan ^{[1
]}

Kozisek, Jozef ^{[1
]}

Linares, Jorge ^{[3
]}

Moncol, Jan ^{[1
]}

Renz, Franz ^{[4
]}

机构：

[1] Slovak Tech Univ FCHPT, Inst Phys Chem, Inst Inorgan Chem, SK-81237 Bratislava, Slovakia

[2] Univ SS Cyril & Methodius, Dept Chem, Trnava, Slovakia

[3] Univ Versailles, Lab GEMAC, UMR CNRS 86, F-78035 Versailles, France

[4] Leibniz Univ Hannover, Inst Inorgan Chem, D-30167 Hannover, Germany

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 09期

关键词：

CRYSTAL-STRUCTURE; BUILDING-BLOCKS; TEMPERATURE; STATE; MULTISTABILITY; ENCAPSULATION; TRANSITIONS; MAGNETISM; COMPOUND; PRESSURE;

D O I：

10.1039/b919120h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Fe-II{(CN)(FeL5)-L-III}(6)]Cl-2 consists of a mixed-valence heptanuclear cyanide-bridged unit formed of a Schiff-base pentadentate ligand L-5 and it shows a spin crossover of the peripheral Fe-III centres.

引用

页码：2198 / 2200

页数：3

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