Spin crossover in a heptanuclear mixed-valence iron complex

被引：42
|
作者：
Boca, Roman [1 ,2 ]
Salitros, Ivan [1 ]
Kozisek, Jozef [1 ]
Linares, Jorge [3 ]
Moncol, Jan [1 ]
Renz, Franz [4 ]
机构：
[1] Slovak Tech Univ FCHPT, Inst Phys Chem, Inst Inorgan Chem, SK-81237 Bratislava, Slovakia
[2] Univ SS Cyril & Methodius, Dept Chem, Trnava, Slovakia
[3] Univ Versailles, Lab GEMAC, UMR CNRS 86, F-78035 Versailles, France
[4] Leibniz Univ Hannover, Inst Inorgan Chem, D-30167 Hannover, Germany
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 09期
关键词：
CRYSTAL-STRUCTURE; BUILDING-BLOCKS; TEMPERATURE; STATE; MULTISTABILITY; ENCAPSULATION; TRANSITIONS; MAGNETISM; COMPOUND; PRESSURE;
D O I：
10.1039/b919120h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex [Fe-II{(CN)(FeL5)-L-III}(6)]Cl-2 consists of a mixed-valence heptanuclear cyanide-bridged unit formed of a Schiff-base pentadentate ligand L-5 and it shows a spin crossover of the peripheral Fe-III centres.
引用
收藏
页码：2198 / 2200
页数：3
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