Visible-Light-Induced Direct Photocatalytic Carboxylation of Indoles with CBr4/MeOH

被引：42

作者：

Yang, Qing-Qing ^{[1
,2
]}

Marchini, Marianna ^{[1
]}

Xiao, Wen-Jing ^{[2
]}

Ceroni, Paola ^{[1
]}

Bandini, Marco ^{[1
]}

机构：

[1] Univ Bologna, Alma Mater Studiorum, Dept Chem G Ciamician, I-40126 Bologna, Italy

[2] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Hubei, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 50期

关键词：

carboxylation; indole functionalization; methanolysis; photocatalysis; visible light; DONOR-ACCEPTOR COMPLEX; PHOTOREDOX CATALYSIS; METAL-FREE; ENANTIOSELECTIVE FUNCTIONALIZATION; RADICAL ADDITIONS; ALCOHOLS; ACTIVATION; ALKYLATION; INDOLE-2-CARBOXAMIDES; CYCLIZATIONS;

D O I：

10.1002/chem.201503787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photocatalysis enables the cascade reactions of indoles and CBr4 in MeOH through a C(sp(2))-H functionalization/methanolysis sequence. The title reaction provides an efficient access to indole 2- and 3-carboxylates in a single operation (no preinstallation of protecting as well as directing groups was required) with good yields under mild reaction conditions.

引用

页码：18052 / 18056

页数：5

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