Intense red and cyan luminescence in europium doped silicate glasses

被引:19
作者
Cao, Ting [1 ,2 ]
Chen, Guitang [1 ,2 ]
Lue, Wancong [1 ,2 ]
Zhou, Han [1 ,2 ]
Li, Jianfu [1 ]
Zhu, Zhaojie [1 ]
You, Zhenyu [1 ]
Wang, Yan [1 ]
Tu, Chaoyang [1 ]
机构
[1] Chinese Acad Sci, Key Lab Mat Chem & Phys, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
关键词
Chemical activity; Silicates; Rare-earths in glasses; IONS;
D O I
10.1016/j.jnoncrysol.2009.08.008
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The photoluminescence properties of silicate glasses, singly doped with europium ions and co-doped with europium ions and Al powder, have been characterized by the absorption, excitation, and emission spectroscopies. The absorption edge in the absorption spectra shows a large red shift from 320 nm to 405 nm. Under near-ultraviolet (NUV) excitation, sample, doped with Eu3+ emit intense red light while those co-doped with Eu3+ and Al give intense cyan emission. The influences of the glass compositions on the spectroscopic properties are also discussed. These glasses may be potential candidates for light-emitting diodes (LEDs). (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2361 / 2364
页数:4
相关论文
共 19 条
  • [1] Blasse G., 1994, Luminescence Material
  • [2] A simple model for f→d transitions of rare-earth ions in crystals
    Duan, CK
    Reid, MF
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2003, 171 (1-2) : 299 - 303
  • [3] FANG BJ, 2007, MAT RES B, V42, P1195
  • [4] Fujita Shunsuke, 2005, Proceedings of the SPIE - The International Society for Optical Engineering, V5941, P594111, DOI 10.1117/12.614668
  • [5] GAN F, 1991, OPTICAL SPECTROSCOPI
  • [6] Suboxide-related centre as the source of the intense red luminescence of porous Si
    Korsunskaya, NE
    Torchinskaya, TV
    Khomenkova, LY
    Dzhumaev, BR
    Prokes, SM
    [J]. MICROELECTRONIC ENGINEERING, 2000, 51-2 : 485 - 493
  • [7] LIN G, 2007, OPT EXPRESS, V15, P25
  • [8] White light emission from Eu3+ in CaIn2O4 host lattices
    Liu, Xiaoming
    Lin, Cuikun
    Lin, Jun
    [J]. APPLIED PHYSICS LETTERS, 2007, 90 (08)
  • [9] Blue emission from Eu2+-doped high silica glass by near-infrared femtosecond laser irradiation
    Qiao, Yanbo
    Chen, Danping
    Ren, Jinjun
    Wu, Botao
    Qiu, Jianrong
    Akai, Tomoko
    [J]. JOURNAL OF APPLIED PHYSICS, 2008, 103 (02)
  • [10] White light with UV LEDs
    Radkov, E
    Bompiedi, R
    Srivastava, AM
    Setlur, AA
    Becker, C
    [J]. THIRD INTERNATIONAL CONFERENCE ON SOLID STATE LIGHTING, 2004, 5187 : 171 - 177