Intense red and cyan luminescence in europium doped silicate glasses

被引:19
作者
Cao, Ting [1 ,2 ]
Chen, Guitang [1 ,2 ]
Lue, Wancong [1 ,2 ]
Zhou, Han [1 ,2 ]
Li, Jianfu [1 ]
Zhu, Zhaojie [1 ]
You, Zhenyu [1 ]
Wang, Yan [1 ]
Tu, Chaoyang [1 ]
机构
[1] Chinese Acad Sci, Key Lab Mat Chem & Phys, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
关键词
Chemical activity; Silicates; Rare-earths in glasses; IONS;
D O I
10.1016/j.jnoncrysol.2009.08.008
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The photoluminescence properties of silicate glasses, singly doped with europium ions and co-doped with europium ions and Al powder, have been characterized by the absorption, excitation, and emission spectroscopies. The absorption edge in the absorption spectra shows a large red shift from 320 nm to 405 nm. Under near-ultraviolet (NUV) excitation, sample, doped with Eu3+ emit intense red light while those co-doped with Eu3+ and Al give intense cyan emission. The influences of the glass compositions on the spectroscopic properties are also discussed. These glasses may be potential candidates for light-emitting diodes (LEDs). (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2361 / 2364
页数:4
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