Self-assembly, crystal structure and photoluminescent properties of a novel organic-inorganic hybrid coordination polymer:: [CdCl3(CH3)3NH]

被引：22

作者：

Ma, Kuirong ^{[1
]}

Xu, Jianing ^{[1
]}

Zhang, Ping ^{[1
]}

Wang, Ying ^{[1
]}

Wang, Li ^{[1
]}

Fan, Yong ^{[1
]}

Song, Tianyou ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

SOLID STATE SCIENCES | 2006年 / 8卷 / 12期

基金：

中国国家自然科学基金;

关键词：

solvothermal synthesis; structure; hybrid; photoluminescent property;

D O I：

10.1016/j.solidstatesciences.2006.09.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel organic-inorganic coordination polymer [CdCl3(CH3)(3)NH] 1 was synthesized by the reaction of CdCl2 with trimethylamine (TMA) at 170 degrees C for 5 days in ethanol and structurally characterized by means of X-ray single diffraction. The title compound affords a one-dimensional chain structure. It crystallizes in hexagonal system space group P6(3)/m with a = 9.1401(13) angstrom, b = 9.1401(13) angstrom, c = 6.7313(13) angstrom, gamma = 120.00 degrees, V = 487.00(14) angstrom(3), Z = 2, DC = 1.895 Mg/m(3), F(000) = 266, Mr = 277.86, mu(Mo K alpha) = 2.99 mm(-1), the final R = 0.0420 and omega R = 0.1020 for 355 observed reflections with I > 2 sigma(1). The title compound consists of cation [(CH3)(3)NH](+) and anion chain [(CdCl3)](n)(-), and they are combined by static attracting forces in the crystal. TG-DTA, XRD and IR data for the title compound are reported and discussed. The photoluminescent properties of the compound 1 were also investigated. (c) 2006 Elsevier Masson SAS. All rights reserved.

引用

页码：1473 / 1476

页数：4

共 17 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].