Characteristics of a Confined Impinging Jet Reactor: Energy Dissipation, Homogeneous and Heterogeneous Reaction Products, and Effect of Unequal Flow

被引:68
作者
Siddiqui, Shad W. [1 ]
Zhao, Yinan [1 ]
Kukukova, Alena [1 ]
Kresta, Suzanne M. [1 ]
机构
[1] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2G6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
IRON-OXIDE NANOPARTICLES; IODATE REACTION SYSTEM; MICROMIXING EFFICIENCY; SCALE-UP; IODIDE; PRECIPITATION; REVISION; KINETICS; METAL;
D O I
10.1021/ie801562y
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The confined impinging jet reactor (CIJR) has attracted wide interest in the past few years because of the efficient micromixing that it offers. In this work, the CUR is characterized over a wide range of mixing conditions, using three measures of performance: estimates of the energy dissipation rate, micromixing efficiency based oil the yield of a homogeneous reaction, and particle size resulting from a heterogeneous precipitation reaction. The energy dissipation results showed very good agreement between four methods, with values tip to 100 times greater than those observed ill Stirred tanks. The reactions showed a higher sensitivity to mixing conditions, at higher concentrations, with less effect of mixing at high flow rates. The operation of the CIA was very robust to changes in flow rate, with stable performance for up to a 30% difference in the inlet flows.
引用
收藏
页码:7945 / 7958
页数:14
相关论文
共 51 条
[1]  
Abel E, 1928, Z PHYS CHEM-STOCH VE, V136, P186
[2]  
Abel E, 1926, Z PHYS CHEM-STOCH VE, V122, P49
[3]   An extension to the incorporation model of micromixing and its use in estimating local specific energy dissipation rates [J].
Assirelli, M. ;
Wynn, E. J. W. ;
Buialski, W. ;
Eaglesham, A. ;
Nienow, A. W. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (10) :3460-3469
[4]   Intensifying micromixing in a semi-batch reactor using a Rushton turbine [J].
Assirelli, M ;
Bujalski, W ;
Eaglesham, A ;
Nienow, AW .
CHEMICAL ENGINEERING SCIENCE, 2005, 60 (8-9) :2333-2339
[5]   DISTRIBUTION OF STRIATION THICKNESS FROM IMPINGEMENT MIXERS IN REACTION INJECTION-MOLDING [J].
BALDYGA, J ;
BOURNE, JR .
POLYMER ENGINEERING AND SCIENCE, 1983, 23 (10) :556-559
[6]  
Barton A.F.M., 1975, J CHEM SOC FARADAY T, V1, P568
[7]   MONODISPERSE COLLOIDS OF TRANSITION-METAL AND LANTHANIDE COMPOUNDS [J].
BEATTIE, JK .
PURE AND APPLIED CHEMISTRY, 1989, 61 (05) :937-941
[8]   Surface feed with minimum by-product formation for competitive reactions [J].
Bhattacharya, S ;
Kresta, SM .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2004, 82 (A9) :1153-1160
[9]  
BHATTACHARYA S, 2005, THESIS U ALBERTA CAN
[10]   Comments on the iodide/iodate method for characterising micromixing [J].
Bourne, John R. .
CHEMICAL ENGINEERING JOURNAL, 2008, 140 (1-3) :638-641