Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry

被引：842

作者：

Roth, Hudson G.

Romero, Nathan A. ^{[1
]}

Nicewicz, David A. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, 125 South Rd, Chapel Hill, NC 27599 USA

来源：

SYNLETT | 2016年 / 27卷 / 05期

基金：

美国国家科学基金会;

关键词：

cyclic voltammetry; photoredox catalysis; redox potential; electron transfer; computational chemistry; DENSITY-FUNCTIONAL THEORY; ACCURATE OXIDATION POTENTIALS; BIPHENYL DERIVATIVES; PHOTOREDOX CATALYSIS; CYCLIC VOLTAMMETRY; APPLICABILITY; REDUCTION; COMPLEXES; ENERGIES; RADICALS;

D O I：

10.1055/s-0035-1561297

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein, we report half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry. These values are of great use in assessing the thermodynamics of an electron-transfer process. In addition, we disclose a simple computational method to determine redox potentials of organic substrates.

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页码：714 / 723

页数：10

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