Recent Advances in Organocatalytic Ring-opening Polymerization

被引：6

作者：

Ji, Mingjun ^{[1
,2
]}

Wu, Mengqi ^{[1
,2
]}

Han, Jiayu ^{[1
,2
]}

Zhang, Fanjun ^{[1
,2
]}

Peng, Hongwei ^{[1
,2
]}

Guo, Lihua ^{[1
,2
]}

机构：

[1] Qufu Normal Univ, Sch Chem & Chem Engn, Key Lab Life Organ Anal, Qufu 273165, Shandong, Peoples R China

[2] Qufu Normal Univ, Sch Chem & Chem Engn, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Shandong, Peoples R China

来源：

CURRENT ORGANIC CHEMISTRY | 2021年 / 25卷 / 02期

关键词：

Ring-opening polymerization; organocatalysts; aliphatic polyesters; phosphazene base; N-heterocyclic carbenes; (thio)urea; N-HETEROCYCLIC CARBENES; EPSILON-CAPROLACTONE; GAMMA-BUTYROLACTONE; HYDROGEN CARBONATES; O-CARBOXYANHYDRIDES; MICHAEL REACTION; ETHYLENE-OXIDE; PRE-CATALYSTS; UREA; VERSATILE;

D O I：

10.2174/1385272824999200917151344

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

As compared with widely used polyolefin materials, aliphatic polyesters have been primarily used in electronics, packaging, and biomedicine owing to its unique biocompatibility and degradability. At present, ring-opening polymerization (ROP) of lactone is the main method to synthesize polyesters. Two types of catalysts, including metal-based catalysts and organocatalysts, were most researched today. However, metal-based catalysts lead to polymer materials with metal residues, which limits its properties and applications. As a result, organocatalysts have received great attention. In this review, the progress of organocatalytic ring-opening polymerization in the past decades was systematically summarized. The potential challenges and development directions in this field are also discussed.

引用

页码：272 / 286

页数：15

共 102 条

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