Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) π-alkene complexes that contain a sterically hindered o-biphenylphosphine ligand

被引：93

作者：

Brown, Timothy J. ^{[1
]}

Dickens, Marina G. ^{[1
]}

Widenhoefer, Ross A. ^{[1
]}

机构：

[1] Duke Univ, French Family Sci Ctr, Durham, NC 27708 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 42期

基金：

美国国家科学基金会;

关键词：

GOLD(I)-CATALYZED INTRAMOLECULAR HYDROAMINATION; ACETYLENE COMPLEXES; CATALYSIS; ETHYLENE; ALLENES; ALKYNES; AU; BOND; CYCLOADDITIONS; REACTIVITY;

D O I：

10.1039/b914632f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A number of cationic gold pi-alkene complexes of the form {[P(t-Bu)(2)o-biphenyl]Au(pi-alkene)} +SbF6- were isolated and three were analyzed by X-ray crystallography.

引用

页码：6451 / 6453

页数：3

共 49 条

[31] SYNTHESIS, STRUCTURES, STABILITIES, AND REACTIONS OF CATIONIC OLEFIN COMPLEXES OF PALLADIUM(II) CONTAINING THE ETA-5-CYCLOPENTADIENYL LIGAND [J].

KUROSAWA, H ;

MAJIMA, T ;

ASADA, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (23) :6996-7003

[32] Homogeneous catalytic hydroamination of alkynes and allenes with ammonia [J].

Lavallo, Vincent ;

Frey, Guido D. ;

Donnadieu, Bruno ;

Soleilhavoup, Michele ;

Bertrand, Guy .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (28) :5224-5228

[33]

Lavallo V, 2007, P NATL ACAD SCI USA, V104, P13569, DOI 10.1073/pnas.0705809104

[34] Gold(I)-Catalyzed Intramolecular Dihydroamination of Allenes with N,N′-Disubstituted Ureas To Form Bicyclic Imidazolidin-2-ones [J].

Li, Hao ;

Widenhoefer, Ross A. .

ORGANIC LETTERS, 2009, 11 (12) :2671-2674

[35] Gold-catalyzed organic transformations [J].

Li, Zigang ;

Brouwer, Chad ;

He, Chuan .

CHEMICAL REVIEWS, 2008, 108 (08) :3239-3265

[36] Synthesis and Structural Characterization of Stable Organogold(I) Compounds. Evidence for the Mechanism of Gold-Catalyzed Cyclizations [J].

Liu, Le-Ping ;

Xu, Bo ;

Mashuta, Mark S. ;

Hammond, Gerald B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (52) :17642-+

[37] Ligand-Controlled Access to [4+2] and [4+3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes [J].

Mauleon, Pablo ;

Zeldin, Rachel M. ;

Gonzalez, Ana Z. ;

Toste, F. Dean .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) :6348-+

[38] Energy partitioning analysis of the bonding in ethylene and acetylene complexes of group 6, 8, and 11 metals:: (CO)5TM-C2Hx and Cl4TM-C2Hx (TM = Cr, Mo, W), (CO)4TM-C2Hx (TM = Fe, Ru, Os), and TM+-C2Hx (TM = Cu, Ag, Au) [J].

Nechaev, MS ;

Rayón, VM ;

Frenking, G .

JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (15) :3134-3142

[39] Intramolecular [4+2] cycloadditions of 1,3-enynes or arylalkynes with alkenes with highly reactive cationic phosphine Au(I) complexes [J].

Nieto-Oberhuber, C ;

López, S ;

Echavarren, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (17) :6178-6179

[40] Synthesis and structural characterization of isolable phosphine coinage metal π-complexes [J].

Shapiro, Nathan D. ;

Toste, F. Dean .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (08) :2779-2782

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