Crystalline and molecular design of functionalized viologens

被引：3

作者：

Gutov, A. V. ^{[1
]}

Rusanov, E. B. ^{[1
]}

Ryabitskii, A. B. ^{[1
]}

Tsimbal, I. F. ^{[1
]}

Chernega, A. N. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2009年 / 79卷 / 09期

关键词：

ACIDS;

D O I：

10.1134/S1070363209090175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The regularities of molecular and crystalline structure of functionalized (including mesoionic) viologens were systematically studied. For this purpose a number of fundamentally new viologenic systems was synthesized containing functional groups in side substituents. As a result of extensive X-ray structural studies it is revealed that unlike "classical" viologens, which in crystal form cation-anion pairs or cation-anion stacks, functionalized viologens are bound into endless chains by means of strong intermolecular hydrogen bonds.

引用

页码：1910 / 1918

页数：9

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