Strong Ultra-Broadband Near-infrared Photoluminescence from Bismuth-Embedded Zeolites and Their Derivatives

被引：95

作者：

Sun, Hong-Tao ^{[1
]}

Hosokawa, Akinobu ^{[2
]}

Miwa, Yuji ^{[1
]}

Shimaoka, Fumiaki ^{[1
]}

Fujii, Minoru ^{[1
]}

Mizuhata, Minoru ^{[2
]}

Hayashi, Shinji ^{[1
]}

Deki, Shigehito ^{[2
]}

机构：

[1] Kobe Univ, Dept Elect & Elect Engn, Kobe, Hyogo 6578501, Japan

[2] Kobe Univ, Dept Chem Sci & Engn, Kobe, Hyogo 6578501, Japan

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 36期

基金：

日本学术振兴会;

关键词：

LOWER OXIDATION STATES; NANOCRYSTALLINE ZEOLITES; INTRAZEOLITIC MIGRATION; THERMAL TREATMENTS; MOLECULAR-SIEVE; DOPED GLASSES; SILICA GLASS; LUMINESCENCE; EMISSION; FILMS;

D O I：

10.1002/adma.200900573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zeolites with embedded bismuth compounds display strong, air-stable, long-lived, ultrabroadband, and tunable near-infrared photoluminescence (see picture). Bismuth ions not only act as luminescence-active centers, but also as blocks for selectively closing the "in-out windows" of water molecules. Bismuth active centers can be sealed in a low-vibrational environment by bismuth agglomerates even when the sample still contains a large amount of water.

引用

页码：3694 / +

页数：6

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