Simple and efficient method for the oxidation of sulfides to sulfones using hydrogen peroxide and a Mo(VI) based catalyst

被引：44

作者：

Jeyakumar, Kandasamy ^{[1
]}

Chakravarthy, Rajan Deepan ^{[1
]}

Chand, Dillip Kumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Chennai 600036, Tamil Nadu, India

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 14期

关键词：

Sulfides; Oxidation; Sulfones; Molybdenum(VI); Hydrogen peroxide; O-IODOXYBENZOIC ACID; SELECTIVE OXIDATION; ORGANIC-SYNTHESIS; SULFOXIDES; H2O2; QUINONES; FACILE; MOLYBDENUM; BROMIDE; PHENOLS;

D O I：

10.1016/j.catcom.2009.07.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple and efficient method for the oxidation of sulfides to sulfones at room temperature using ammonium heptamolybdate and 30% H2O2 is developed. The reactions provide excellent yields within short time, also sensitive functional groups such as allyl, vinyl, propargyl, alcohol, ketone. ester, pyridine and nitrile are found to be tolerated. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1948 / 1951

页数：4

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