Enantioselective transesterification catalysis by Candida antarctica lipase immobilized on superparamagnetic nanoparticles

被引:45
|
作者
Netto, Caterina G. C. M. [2 ]
Andrade, Leandro H. [1 ]
Toma, Henrique E. [2 ]
机构
[1] Univ Sao Paulo, Inst Quim, Lab Fine Chem & Biocatalysis, Sao Paulo, Brazil
[2] Univ Sao Paulo, Inst Quim, Supramol NanotechLab, Sao Paulo, Brazil
基金
巴西圣保罗研究基金会;
关键词
RUGOSA LIPASE; SUPPORT; SELECTIVITY; IMPROVEMENT; STABILITY;
D O I
10.1016/j.tetasy.2009.08.022
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Lipase B from Candida antarctica can be directly immobilized onto functionalized superparamagnetic nanoparticles, preserving its enzymatic activity in the enantioselective transesterification of secondary alcohols, with excellent results in terms of enantiomeric discrimination. The immobilized enzyme can be easily recovered with a magnet, allowing its reuse with negligible loss of activity. (C) 2009 Elsevier Ltd. All rights reserved
引用
收藏
页码:2299 / 2304
页数:6
相关论文
共 50 条
  • [1] Enantioselective transesterification by Candida antarctica Lipase B immobilized on fumed silica
    Kramer, Martin
    Cruz, Juan C.
    Pfromm, Peter H.
    Rezac, Mary E.
    Czermak, Peter
    JOURNAL OF BIOTECHNOLOGY, 2010, 150 (01) : 80 - 86
  • [2] Regeneration of immobilized Candida antarctica lipase for transesterification
    Chen, JW
    Wu, WT
    JOURNAL OF BIOSCIENCE AND BIOENGINEERING, 2003, 95 (05) : 466 - 469
  • [3] Enantioselective transesterification of a tertiary alcohol by lipase A from Candida antarctica
    Krishna, SH
    Persson, M
    Bornscheuer, UT
    TETRAHEDRON-ASYMMETRY, 2002, 13 (24) : 2693 - 2696
  • [4] Resolution of (±)-menthol by immobilized Candida rugosa lipase on superparamagnetic nanoparticles
    Shu, B
    Zheng, G
    Wei, L
    Yan, S
    FOOD CHEMISTRY, 2006, 96 (01) : 1 - 7
  • [5] Immobilized Candida antarctica lipase B (CALB) on functionalized MCM-41: Stability and catalysis of transesterification of soybean oil and phytosterol
    Yu, Dianyu
    Zhang, Xin
    Wang, Tong
    Geng, Haoyuan
    Wang, Liqi
    Jiang, Lianzhou
    Elfalleh, Walid
    FOOD BIOSCIENCE, 2021, 40
  • [6] Enantioselective transesterification of a propargyl tertiary alcohol by Candida antarctica lipase A: A reaction medium engineering approach
    Neto, Laerte Ganeo
    Milagre, Cintia Duarte Freitas
    Milagre, Humberto Marcio Santos
    RESULTS IN CHEMISTRY, 2023, 5
  • [7] Liquid carbon dioxide as an effective solvent for immobilized Candida antarctica lipase B catalyzed transesterification
    Hoang, Hai Nam
    Matsuda, Tomoko
    TETRAHEDRON LETTERS, 2015, 56 (04) : 639 - 641
  • [8] Transesterification of a Tertiary Alcohol by Engineered Candida antarctica Lipase A
    Lofgren, Johanna
    Gorbe, Tamas
    Oschmann, Michael
    Humble, Maria Svedendahl
    Backvall, Jan-E
    CHEMBIOCHEM, 2019, 20 (11) : 1438 - 1443
  • [9] Superparamagnetic iron oxide nanoparticles (SPIONs) conjugated with lipase Candida antarctica A for biodiesel synthesis
    Peffi Ferreira, Luis Fernando
    Mazzi de Oliveira, Thayna
    Toma, Sergio Hiroshi
    Toyama, Marcos Makoto
    Araki, Koiti
    Avanzi, Luis Humberto
    RSC ADVANCES, 2020, 10 (63) : 38490 - 38496
  • [10] SPECIFICITY OF CANDIDA-ANTARCTICA LIPASE-B (SP-435) IN THE PRESENCE OF LIPASE-A IN A DOUBLE ENANTIOSELECTIVE TRANSESTERIFICATION
    THEIL, F
    BJORKLING, F
    BIOTECHNOLOGY LETTERS, 1993, 15 (06) : 605 - 608