Study of the ternary system CaCl2-NaCl-CaO by DSC

被引:19
作者
Freidina, EB [1 ]
Fray, DJ [1 ]
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
基金
英国工程与自然科学研究理事会;
关键词
differential scanning calorimetry (DSC); calcium chloride; sodium chloride; calcium oxide; phase diagram;
D O I
10.1016/S0040-6031(00)00454-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
The chloride-rich part of the ternary system CaCl2-NaCl-CaO has been investigated. Ten vertical cross sections below 20 mol% CaO were studied by differential scanning calorimetry. A liquidus surface corresponding to primary crystallisation of CaCl2 and three secondary crystallisation lines was determined. The constructed ternary phase diagram was found to be of a simple eutectic type, E=500 degrees C (48 mol% CaCl2, 47 mol% NaCl, 5 mol% CaO) is suspected. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:97 / 100
页数:4
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