Novel microporous cobalt phosphonate: Efficient heterogeneous catalyst towards oxygen evolution reaction

被引：7
作者：
Xu, Wenbin [1 ]
Feng, Li [2 ]
Wang, Zhiyong [3 ]
Liu, Bingzhi [2 ]
Li, Xuhao [2 ]
Chen, Yuning [2 ]
机构：
[1] Nanchang Urban Planning & Design Inst, 599 Chunhui Rd, Nanchang 330038, Jiangxi, Peoples R China
[2] Guangdong Univ Technol, Sch Civil & Transportat Engn, Guangzhou 510006, Guangdong, Peoples R China
[3] Shenyang Univ Technol, Dept Basic Course, Shenyang 111003, Liaoning, Peoples R China
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2020年 / 879卷
基金：
中国国家自然科学基金;
关键词：
Cobalt phosphonate; Nanocrystalline materials; Porous materials; Electrocatalyst; OER; WATER OXIDATION; PHOSPHATE; HYBRID; ELECTROCATALYSTS; OXIDE; NANOPARTICLES; PERFORMANCE; CO;
D O I：
10.1016/j.jelechem.2020.114786
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
In recent years, organic-inorganic hybrid transition metal-based phosphonate nanomaterials have gained immense attention due to their high electrocatalytic efficiency in oxygen evolution reaction (OER). Newly synthesized porous cobalt-based phosphonate materials i.e. CoNTO-1-3 and CoNTO-1-4 have been synthesized using nitrilotri (methylphosphonic acid) under the hydrothermal reaction condition without utilization of any structure directing agent. Among them, CoNTO-1-3 material displays high catalytic activity towards electrochemical OER having low overpotential value of 312 mV at 10 mA cm(-2) current density in 1.0 M basic (KOH) solution where Tafel slope was 61.1 mV dec(-1). Also, CoNTO-1-3 catalyst exhibits the good stability up to 25 h.
引用
收藏
页数：6
相关论文
共 32 条
  • [1] Fabrication of CoP based nanocomposite as an electrocatalyst for oxygen- and hydrogen-evolving energy conversion reactions
    Ahamad, Tansir
    Naushad, Mu
    Alshehri, Saad M.
    [J]. MATERIALS LETTERS, 2020, 278
  • [2] High-Dielectric Polymer Composite Materials from a Series of Mixed-Metal Phenylphosphonates, ATi(C6H5PO3)3 for Dielectric Energy Storage
    Barber, Peter
    Pellechia, Perry J.
    Ploehn, Harry J.
    zur Loye, H. -C.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (09) : 2553 - 2559
  • [3] Microporous nickel phosphonate derived heteroatom doped nickel oxide and nickel phosphide: Efficient electrocatalysts for oxygen evolution reaction
    Bhanja, Piyali
    Kim, Yena
    Paul, Bappi
    Kaneti, Yusuf Valentino
    Alothman, Asma A.
    Bhaumik, Asim
    Yamauchi, Yusuke
    [J]. CHEMICAL ENGINEERING JOURNAL, 2021, 405
  • [4] Novel porous metal phosphonates as efficient electrocatalysts for the oxygen evolution reaction
    Bhanja, Piyali
    Kim, Yena
    Kani, Kenya
    Paul, Bappi
    Debnath, Tanay
    Lin, Jianjian
    Bhaumik, Asim
    Yamauchi, Yusuke
    [J]. CHEMICAL ENGINEERING JOURNAL, 2020, 396
  • [5] Facile Synthesis of Nanoporous Transition Metal-Based Phosphates for Oxygen Evolution Reaction
    Bhanja, Piyali
    Kim, Yena
    Paul, Bappi
    Lin, Jianjian
    Alshehri, Saad M.
    Ahamad, Tansir
    Kaneti, Yusuf Valentino
    Bhaumik, Asim
    Yamauchi, Yusuke
    [J]. CHEMCATCHEM, 2020, 12 (07) : 2091 - 2096
  • [6] New Hybrid Iron Phosphonate Material as an Efficient Catalyst for the Synthesis of Adipic Acid in Air and Water
    Bhanja, Piyali
    Ghosh, Kajari
    Islam, Sk Safikul
    Patra, Astam K.
    Islam, Sk. Manirul
    Bhaumik, Asim
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (12): : 7147 - 7157
  • [7] Organic-Inorganic Hybrid Metal Phosphonates as Recyclable Heterogeneous Catalysts
    Bhanja, Piyali
    Bhaumik, Asim
    [J]. CHEMCATCHEM, 2016, 8 (09) : 1607 - 1616
  • [8] Organic-Inorganic Cobalt-Phosphonate-Derived Hollow Cobalt Phosphate Spherical Hybrids for Highly Efficient Oxygen Evolution
    Chen, Lei
    Ren, Jin-Tao
    Wang, Yan-Su
    Tian, Wen-Wen
    Gao, Li-Jiao
    Yuan, Zhong-Yong
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (15) : 13559 - 13568
  • [9] Calcined Nickel-Cobalt Mixed Metal Phosphonate with Efficient Electrocatalytic Activity for Oxygen Evolution Reaction
    Feng, Pingjing
    Cheng, Xian
    Li, Jintang
    Luo, Xuetao
    [J]. CHEMISTRYSELECT, 2018, 3 (02): : 760 - 764
  • [10] Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0-14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity
    Gerken, James B.
    McAlpin, J. Gregory
    Chen, Jamie Y. C.
    Rigsby, Matthew L.
    Casey, William H.
    Britt, R. David
    Stahl, Shannon S.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (36) : 14431 - 14442
1234