Mesostructured TUD-1 supported molybdophosphoric acid (HPMo/TUD-1) catalysts for n-heptane hydroisomerization

被引：29

作者：

Liu, Dapeng ^{[1
]}

Quek, Xian-Yang ^{[1
]}

Hu, Shuangquan ^{[1
]}

Li, Lusi ^{[1
]}

Lim, Hui Min ^{[1
]}

Yang, Yanhui ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore

来源：

CATALYSIS TODAY | 2009年 / 147卷

关键词：

TUD-1; HPMo; Bifunctional catalysts; n-Heptane hydroisomerization; CESIUM HYDROGEN SALTS; HETEROPOLY ACIDS; SKELETAL ISOMERIZATION; PENTANE ISOMERIZATION; ALKANES; NMR; DISPROPORTIONATION; STABILITY; HEXANE; RAMAN;

D O I：

10.1016/j.cattod.2009.07.017

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Mesoporous molecular sieves TUD-1 (Technische Universiteit Delft) supported molybodophosphoric acid (HPMo) catalysts with various loadings of active HPMo, component (10-50 wt.%) were prepared and characterized using X-ray diffraction, thermal analysis, infrared spectroscopy, Raman spectroscopy and temperature-programmed desorption of ammonia. The characterization results revealed that HPMo was highly dispersed over TUD-1 support in the samples with HPMo loading no more than 30 wt.%. The supported catalysts were tested in the hydroisomerization of n-heptane at atmosphere pressure in the temperature range of 200-350 degrees C. The optimal HPMo content for the reaction was found around 30 wt.%. High isomer selectivity and superior long-term stability were observed over this catalyst. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：S51 / S57

页数：7

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