Dinuclear Rhombic Copper(I) Iodide Complexes with Rigid Bidentate Arsenic Ligands

被引：9

作者：

Kobayashi, Ryosuke ^{[1
]}

Kihara, Hyota ^{[1
]}

Kusukawa, Takahiro ^{[1
]}

Imoto, Hiroaki ^{[1
,2
]}

Naka, Kensuke ^{[1
,2
]}

机构：

[1] Kyoto Inst Technol, Grad Sch Sci & Technol, Fac Mol Chem & Engn, Sakyo Ku, Goshokaido Cho, Kyoto 6068585, Japan

[2] Kyoto Inst Technol, Mat Innovat Lab, Sakyo Ku, Goshokaido Cho, Kyoto 6068585, Japan

来源：

CHEMISTRY LETTERS | 2021年 / 50卷 / 02期

关键词：

Arsenic; Copper; Cuprophilic interaction; CONSTRUCTION; PLATINUM; EMISSION; CLUSTERS; HALIDES; BR;

D O I：

10.1246/cl.200763

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have recently developed a series of arsenic ligands based on practical synthetic strategies. Herein, three kinds of bidentate arsenic ligands with rigid linkers were selected to construct dinuclear rhombic copper(I) iodide (CuI) complexes, whose structures were analyzed by X-ray crystallography. They had sufficient solubility in organic solvents, and it was confirmed that their coordination forms were kept in the solutions. Intense solid-state emissions were observed even at room temperature, and the emission colors were varied from yellow to red by the ligands.

引用

收藏

页码：382 / 385

页数：4

相关论文

共 48 条

[1] Synthesis of dual emitting iodocuprates: can solvents switch the reaction outcome? [J].

Artem'ev, Alexander, V ;

Berezin, Alexey S. ;

Taidakov, Ilya, V ;

Bagryanskaya, Irina Yu .

INORGANIC CHEMISTRY FRONTIERS, 2020, 7 (11) :2195-2203

[2] Smart composite films of nanometric thickness based on copper-iodine coordination polymers. Toward sensors [J].

Conesa-Egea, Javier ;

Nogal, Noemi ;

Ignacio Martinez, Jose ;

Fernandez-Moreira, Vanesa ;

Rodriguez-Mendoza, Ulises R. ;

Gonzalez-Platas, Javier ;

Gomez-Garcia, Carlos J. ;

Delgado, Salome ;

Zamora, Felix ;

Amo-Ochoa, Pilar .

CHEMICAL SCIENCE, 2018, 9 (41) :8000-8010

[3] Self-assembled 2D supramolecular networks of copper(I) carborane complexes through C-H ⋯ H-B dihydrogen bonding interactions [J].

Department of Chemistry, Liaocheng University, Liaocheng, 252059, China ;

不详 .

Dalton Trans., 2008, 31 (4152-4156) :4152-4156

[4] PHOTOCHEMICAL AND PHOTOPHYSICAL STUDIES OF TETRANUCLEAR COPPER(I) HALIDE CLUSTERS - AN OVERVIEW [J].

FORD, PC .

COORDINATION CHEMISTRY REVIEWS, 1994, 132 :129-140

[5]

Frisch M. J., 2016, GAUSSIAN 16 REV B01, V16

[6] Cu4I4-cubane clusters based on 10-(aryl)phenoxarsines and their luminescence [J].

Galimova, Milyausha F. ;

Zueva, Ekaterina M. ;

Dobrynin, Alexey B. ;

Samigullina, Aida I. ;

Musin, Rustem R. ;

Musina, Elvira I. ;

Karasik, Andrey A. .

DALTON TRANSACTIONS, 2020, 49 (02) :482-491

[7] Synthesis, Structure, and Luminescence of Copper(I) Halide Complexes of Chiral Bis(phosphines) [J].

Gibbons, Sarah K. ;

Hughes, Russell P. ;

Glueck, David S. ;

Royappa, A. Timothy ;

Rheingold, Arnold L. ;

Arthur, Robert B. ;

Nicholas, Aaron D. ;

Patterson, Howard H. .

INORGANIC CHEMISTRY, 2017, 56 (21) :12809-12820

[8] Luminescence mechanochromism of copper iodide clusters: a rational investigation [J].

Huitorel, Brendan ;

Utrera-Melero, Raquel ;

Massuyeau, Florian ;

Mevelec, Jean-Yves ;

Baptiste, Benoit ;

Polian, Alain ;

Gacoin, Thierry ;

Martineau-Corcos, Charlotte ;

Perruchas, Sandrine .

DALTON TRANSACTIONS, 2019, 48 (22) :7899-7909

[9] Evaluation of Ligands Effect on the Photophysical Properties of Copper Iodide Clusters [J].

Huitorel, Brendan ;

El Moll, Hani ;

Utrera-Melero, Raquel ;

Cordier, Marie ;

Fargues, Alexandre ;

Garcia, Alain ;

Massuyeau, Florian ;

Martineau-Corcos, Charlotte ;

Fayon, Franck ;

Rakhmatullin, Aydar ;

Kahlal, Samia ;

Saillard, Jean-Yves ;

Gacoin, Thierry ;

Perruchas, Sandrine .

INORGANIC CHEMISTRY, 2018, 57 (08) :4328-4339

[10] Construction of a Bidentate Arsenic Ligand Library Starting from a Cyclooligoarsine [J].

Imoto, Hiroaki ;

Konishi, Masafumi ;

Nishiyama, Shintaro ;

Sasaki, Hiroshi ;

Tanaka, Susumu ;

Yumura, Takashi ;

Naka, Kensuke .

CHEMISTRY LETTERS, 2019, 48 (11) :1312-1315

← 1 2 3 4 5 →