Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime.: 2.: Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2•2[2-NC5H4(Me)C=NOH]

被引：21

作者：

Sharma, V

Sharma, RK

Bohra, R ^{[1
]}

Jain, VK

Drake, JE

Light, ME

Hursthouse, MB

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

[2] Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India

[3] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

[4] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 664卷 / 1-2期

基金：

英国工程与自然科学研究理事会; 加拿大自然科学与工程研究理事会;

关键词：

tetraorganodistannoxanes; internally functionalized oxime; crystal structures;

D O I：

10.1016/S0022-328X(02)01904-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [{Me2Sn(ON=C(Me)C5H4N)}(2)O}](2).2[2-NC5H4(Me)C=NOH] was obtained during the reaction of Me2SnCl2 with the sodium salt of the ligand in 1:2 molar ratio in a refluxing methanol-benzene mixture. X-ray diffraction analysis of the compound reveals that it is the first tetraorganodistannoxane structural motif in which two molecules of free oxime are connected to the stannoxane framework and the two Sn-O distances of the four-membered planar Sn2O2 ring are identical. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：66 / 69

页数：4

共 21 条

[1] A TETRANUCLEAR BETA-DIKETONATO COMPLEX OF ORGANOTIN(IV) - SYNTHESIS AND CRYSTAL-STRUCTURE OF (BENZOYLTRIFLUOROACETONATO)-(TRIFLUOROACETATO)TETRAMETHYLDISTANNOXANE DIMER [(C6H5C(O)CHCO(CF3)SN(CH3)2)O(SN(CH3)2O2CCF3)]2
AGARWAL, BK
SINGH, YP
BOHRA, R
SRIVASTAVA, G
RAI, AK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 444 (1-2) : 47 - 51
[2] Hydrolysis of bis((trimethylsilyl)methyl)tin dihalides.: Crystallographic and spectroscopic study of the hydrolysis pathway
Beckmann, J
Henn, M
Jurkschat, K
Schürmann, M
Dakternieks, D
Duthie, A
[J]. ORGANOMETALLICS, 2002, 21 (01) : 192 - 202
[3] Outlier treatment in data merging
Blessing, RH
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1997, 30 : 421 - 426
[4] AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY
BLESSING, RH
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 : 33 - 38
[5] VAN DER WAALS VOLUMES + RADII
BONDI, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
[6] Extending distannoxane double ladders using rigid spacers:: A double ladder with eight chiral tin atoms -: and a twist!
Dakternieks, D
Duthie, A
Zobel, B
Jurkschat, K
Schürmann, M
Tiekink, ERT
[J]. ORGANOMETALLICS, 2002, 21 (04) : 647 - 652
[7] Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI [DOI 10.1107/S0021889899006020, 10.1107/S0021889899006020]
[8] HUCKEL W, 1932, LIEBIGS ANN CHEM, V498, P176
[9] JAIN VK, 1996, P INDIAN ACAD SCI, V103, P165
[10] JAIN VK, 1992, MAG RESON CHEM, V30, P158

← 1 2 3 →