Chemoselective cross-metathesis reaction between electron-deficient 1,3-dienes and olefins

被引：42

作者：

Ferrie, Laurent ^{[1
]}

Amans, Dominique ^{[1
]}

Reymond, Sebastien ^{[1
]}

Bellosta, Veronique ^{[1
]}

Capdevielle, Patrice ^{[1
]}

Cossy, Janine ^{[1
]}

机构：

[1] Ecole Super Phys & Chim Ind Ville Paris, CNRS, Chim Organ Lab, F-75231 Paris 05, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 24-25期

关键词：

cross-metathesis; methyl sorbate; dienic amides;

D O I：

10.1016/j.jorganchem.2006.09.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chemoselective cross-metathesis reactions between methyl sorbate or 1,3-dienic amides and various olefins in the presence of the Grubbs-Hoveyda catalyst have been investigated. Cross-metathesis reactions turned out to be more chemoselective with 1,3-dienic amides than with 1,3-dienic esters. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：5456 / 5465

页数：10

共 43 条

[1]

ANDLE S, 2001, CHEM COMMUN, P1692

[2]

Armstrong S.K., 1998, J. Chem. Soc., V1, P371

[3]

Basu K, 2002, ADV SYNTH CATAL, V344, P615, DOI 10.1002/1615-4169(200208)344:6/7<615::AID-ADSC615>3.0.CO

[4]

2-O

[5] LIVING RING-OPENING METATHESIS POLYMERIZATION OF 2,3-DIFUNCTIONALIZED NORBORNADIENES BY MO(CH-TERT-BU)(N-2,6-C6H3-ISO-PR2)(O-TERT-BU)2 [J].

BAZAN, GC ;

KHOSRAVI, E ;

SCHROCK, RR ;

FEAST, WJ ;

GIBSON, VC ;

OREGAN, MB ;

THOMAS, JK ;

DAVIS, WM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (23) :8378-8387

[6] LIVING RING-OPENING METATHESIS POLYMERIZATION OF 2,3-DIFUNCTIONALIZED 7-OXANORBORNENES AND 7-OXANORBORNADIENES BY MO(CHCME2R)(N-2,6-C6H3-ISO-PR2)(O-TERT-BU)2 AND MO(CHCME2R)(N-2,6-C6H3-ISO-PR2)(OCME2CF3)2 [J].

BAZAN, GC ;

OSKAM, JH ;

CHO, HN ;

PARK, LY ;

SCHROCK, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :6899-6907

[7] Highly concise routes to epothilones: The total synthesis and evaluation of epothilone 490 [J].

Biswas, K ;

Lin, H ;

Njardarson, JT ;

Chappell, MD ;

Chou, TC ;

Guan, YB ;

Tong, WP ;

He, LF ;

Horwitz, SB ;

Danishefsky, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) :9825-9832

[8] Olefin metathesis - recent applications in synthesis [J].

Blechert, S .

PURE AND APPLIED CHEMISTRY, 1999, 71 (08) :1393-1399

[9]

Cabrejas LMM, 1999, ANGEW CHEM INT EDIT, V38, P2443

[10]

Cesati RR, 2004, J AM CHEM SOC, V126, P96

← 1 2 3 4 5 →