Chlorocarbonyl ruthenium(II) complexes of tripodal triphos {MeC(CH2PPh2)3}: Synthesis, characterization and catalytic applications in transfer hydrogenation of carbonyl compounds

被引：31

作者：

Sarmah, Bhaskar Jyoti ^{[1
]}

Dutta, Dipak Kumar ^{[1
]}

机构：

[1] CSIR, NE Inst Sci & Technol, Div Mat Sci, Jorhat 785006, Assam, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 06期

关键词：

Ruthenium carbonyl complexes; Tridentate ligands; Triphos complexes; Crystal structure; Transfer hydrogenation; POLYPHOSPHINE LIGANDS; RHODIUM COMPLEXES; METAL-COMPLEXES; PHOSPHINE; HYDROFORMYLATION; 3,5-DI-TERT-BUTYLCATECHOL; HYDROGENOLYSIS; CATECHOLATE; TRIDENTATE; OXIDATION;

D O I：

10.1016/j.jorganchem.2010.01.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Ru(CO)(2)(triphos-kappa P-2)Cl-2] (1) underwent decarbonylation in dichloromethane solution under air over a period of about two weeks to afford the chelated monocarbonyl complex [Ru(CO)(triphos-kappa P-3)Cl-2] (2). The Single Crystal X-ray structure of 2 showed a slightly distorted metal centred complex. The catalytic activity of one of the complexes [Ru(CO)(triphos-kappa P-3)Cl-2] (2) was examined in the transfer hydrogenation of aromatic carbonyl compounds and was found to be efficient with conversion up to 100% in the presence of isopropanol/NaOH. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：781 / 785

页数：5

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