X-ray crystal structure of 2-styrylpyridine

被引:7
作者
Percino, MJ [1 ]
Chapela, VM [1 ]
Salmon, M [1 ]
EspinosaPerez, G [1 ]
Herrera, AM [1 ]
Flores, A [1 ]
机构
[1] UNIV NACL AUTONOMA MEXICO, INST QUIM, COYOACAN 04510, DF, MEXICO
关键词
2-styrylpyridine; 2-stilbazole; single crystal X-ray structure;
D O I
10.1007/BF02576446
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We have crystallized the 2-styrylpyridine from the condensation reaction between the 2-methylpyridine with benzaldehyde in the formation of the model compound 2-styrylpyridine. The X-ray structure and NMR are currently reported. The main features of the structure is that it shows a localization of the double bonds rather than a delocalization of pi electrons in an aromatic fashion.
引用
收藏
页码:549 / 552
页数:4
相关论文
共 6 条
[1]  
CLAVREUL R, 1987, MAKROMOL CHEM, V188, P47
[2]   Condensation of aldehyde collidines and α,γ-lutidine with aldehydes [J].
Langer, G .
BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1905, 38 :3704-3709
[3]   The reaction between 2-picoline and aromatic aldehydes [J].
Shaw, BD ;
Wagstaff, EA .
JOURNAL OF THE CHEMICAL SOCIETY, 1933, :77-79
[4]  
*SIEM AN XRAY INST, 1993, SHELXTL PLUS PC US M
[5]   Crystal structure of 5-ethyl-2-pyridylvinylbenzene [J].
SorianoGarcia, M ;
Panneerselvam, K ;
JimenezEstrada, M ;
Chavarin, C ;
Manero, O .
ANALYTICAL SCIENCES, 1996, 12 (06) :1001-1002
[6]   A COMPARISON OF METHODS FOR PREPARATION OF 2- AND 4-STYRYLPYRIDINES [J].
WILLIAMS, JL ;
CARLSON, JM ;
BORDEN, DG ;
FORD, JA ;
ADEL, RE ;
REYNOLDS, GA .
JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (02) :387-&