(R)-(+)-2,2′-bis(diphenylphosphinoyl)1,1′-binaphthyl

被引:0
作者
Bunten, KA [1 ]
Farrar, DH [1 ]
Lough, AJ [1 ]
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, BINAP oxide, C44H32O2P2, (I), was synthesized by direct oxidation of (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) with tert-butyl hydroperoxide in toluene solution. The angle between the naphthyl planes of the binaphthyl group is 94.17 (3)degrees.
引用
收藏
页码:E267 / E267
页数:1
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