Ultra-thin and porous MoSe2 nanosheets: facile preparation and enhanced electrocatalytic activity towards the hydrogen evolution reaction

被引:121
作者
Lei, Zhouyue
Xu, Shengjie
Wu, Peiyi [1 ]
机构
[1] Fudan Univ, State Key Lab Mol Engn Polymers, Collaborat Innovat Ctr Polymers & Polymer Composi, Dept Macromol Sci, Shanghai 200433, Peoples R China
基金
美国国家科学基金会;
关键词
LARGE-AREA; LIQUID EXFOLIATION; FILMS;
D O I
10.1039/c5cp06483j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, ultra-thin and porous molybdenum selenide (MoSe2) nanosheets were prepared through a modified liquid exfoliation method as efficient electrocatalysts for the hydrogen evolution reaction (HER). This novel structure enables the exposure of more catalytically active sites and moreover maintains effective electron transport, resulting in a small peak potential of similar to 75 mV as well as long-term durability. In addition, due to the facile and economical preparation method as well as its eco-friendly synthetic conditions, this study provides a high-performance HER catalyst with promising commercial application prospects.
引用
收藏
页码:70 / 74
页数:5
相关论文
共 37 条
[31]   Controllable Disorder Engineering in Oxygen-Incorporated MoS2 Ultrathin Nanosheets for Efficient Hydrogen Evolution [J].
Xie, Junfeng ;
Zhang, Jiajia ;
Li, Shuang ;
Grote, Fabian ;
Zhang, Xiaodong ;
Zhang, Hao ;
Wang, Ruoxing ;
Lei, Yong ;
Pan, Bicai ;
Xie, Yi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (47) :17881-17888
[32]   Defect-Rich MoS2 Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution [J].
Xie, Junfeng ;
Zhang, Hao ;
Li, Shuang ;
Wang, Ruoxing ;
Sun, Xu ;
Zhou, Min ;
Zhou, Jingfang ;
Lou, Xiong Wen ;
Xie, Yi .
ADVANCED MATERIALS, 2013, 25 (40) :5807-+
[33]   Facile preparation of 3D MoS2/MoSe2 nanosheet-graphene networks as efficient electrocatalysts for the hydrogen evolution reaction [J].
Xu, Shengjie ;
Lei, Zhouyue ;
Wu, Peiyi .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (31) :16337-16347
[34]   One-Pot, Facile, and Versatile Synthesis of Monolayer MoS2/WS2 Quantum Dots as Bioimaging Probes and Efficient Electrocatalysts for Hydrogen Evolution Reaction [J].
Xu, Shengjie ;
Li, Dian ;
Wu, Peiyi .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (07) :1127-1136
[35]   Large-Area Vapor-Phase Growth and Characterization of MoS2 Atomic Layers on a SiO2 Substrate [J].
Zhan, Yongjie ;
Liu, Zheng ;
Najmaei, Sina ;
Ajayan, Pulickel M. ;
Lou, Jun .
SMALL, 2012, 8 (07) :966-971
[36]   "Chemical Weathering" Exfoliation of Atom-Thick Transition Metal Dichalcogenides and Their Ultrafast Saturable Absorption Properties [J].
Zhao, Gang ;
Han, Shuo ;
Wang, Aizhu ;
Wu, Yongzhong ;
Zhao, Mingwen ;
Wang, Zhengping ;
Hao, Xiaopeng .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (33) :5292-5299
[37]   Toward Design of Synergistically Active Carbon-Based Catalysts for Electrocatalytic Hydrogen Evolution [J].
Zheng, Yao ;
Jiao, Yan ;
Li, Lu Hua ;
Xing, Tan ;
Chen, Ying ;
Jaroniec, Mietek ;
Qiao, Shi Zhang .
ACS NANO, 2014, 8 (05) :5290-5296