Removal of siloxane from digestion gas of sewage sludge

被引:79
作者
Matsui, Toru [1 ]
Imamura, Shigeru [2 ]
机构
[1] Tokyo Gas Co Ltd, Tech Res Inst, Tsurumi Ku, Yokohama, Kanagawa 2300045, Japan
[2] Mitsui Zosen Environm Engn Cooperat, Environm Solut Headquarters, Edogawa Ku, Tokyo 134008, Japan
关键词
Sewage sludge; Anaerobic digestion; Siloxane; Activated carbon; WASTE-ACTIVATED-SLUDGE; BIOGAS; SULFIDE;
D O I
10.1016/j.biortech.2009.05.037
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
This paper studies the way to remove siloxanes from digestion gas of sewage sludge by adsorbents. Many adsorbents were tested by using the model gas of siloxane in nitrogen. The adsorption ratio was 0.056-0.192 for the activated carbons, 0.004-0.077 for the molecular sieve and 0.104 for the silica gel. An observed tendency was that the activated carbons showed high adsorption ratio, and that the adsorption ratio was increased when BET surface area was higher, and the pore volume was higher and the pH value was higher. Finally, we found a few kinds of activated carbons with the Superior ability of adsorption, and we tested the ability of them by using the real digestion gas. All of the siloxanes were found to be removed in the 1000 h test. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:S29 / S32
页数:4
相关论文
共 19 条
[1]   A review of biogas purification processes [J].
Abatzoglou, Nicolas ;
Boivin, Steve .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2009, 3 (01) :42-71
[2]   Principles and potential of the anaerobic digestion of waste-activated sludge [J].
Appels, Lise ;
Baeyens, Jan ;
Degreve, Jan ;
Dewil, Raf .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2008, 34 (06) :755-781
[3]   pH of activated carbon surface as an indication of its suitability for H2S removal from moist air streams [J].
Bagreev, A ;
Adib, F ;
Bandosz, TJ .
CARBON, 2001, 39 (12) :1897-1905
[4]   Energy use of biogas hampered by the presence of siloxanes [J].
Dewil, R ;
AppelS, L ;
BaeyenS, J .
ENERGY CONVERSION AND MANAGEMENT, 2006, 47 (13-14) :1711-1722
[5]   The analysis of volatile siloxanes in waste activated sludge [J].
Dewil, Raf ;
Appels, Lise ;
Baeyens, Jan ;
Buczynska, Anna ;
Van Vaeck, Luc .
TALANTA, 2007, 74 (01) :14-19
[6]  
Hagmann M., 2002, SOFW-J, V128, P3
[7]  
HAPPMANN R, 1996, FRESENIUS J ANALYTIC, V354, P66
[8]   Air-water partition constants for volatile methyl siloxanes [J].
Kochetkov, A ;
Smith, JS ;
Ravikrishna, R ;
Valsaraj, KT ;
Thibodeaux, LJ .
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 2001, 20 (10) :2184-2188
[9]  
Lee SH, 2001, J IND ENG CHEM, V7, P276
[10]  
LEWIS FM, 2008, WATER ENV TECHNOLOGY, V20, P64