Hydrodefluorination Reactions Catalyzed by Transition-Metal Complexes

被引：34

作者：

Hu, Ji-Yun ^{[1
]}

Zhang, Jun-Long ^{[1
]}

机构：

[1] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

ORGANOMETALLIC FLUORINE CHEMISTRY | 2015年 / 52卷

关键词：

Catalysis; C-F activation; Hydrodefluorination; Transition metals; C-F BOND; CARBON-FLUORINE BONDS; ELECTRON-DEFICIENT POLYFLUOROARENES; GEM-DIFLUOROMETHYLENE DERIVATIVES; OXIDATIVE ADDITION; COUPLING REACTIONS; CRYSTAL-STRUCTURE; H BONDS; POLYFLUORINATED PYRIDINES; ORGANOMETALLIC CHEMISTRY;

D O I：

10.1007/3418_2015_92

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Activation of the C-F bond by transition-metal catalysts not only advances fundamental understanding of the formation and reactivity of organometallic fluoride complexes but also provides a potential approach to partially fluorinated organic compounds from readily available perfluorinated bulk chemicals. Hydrodefluorination (HDF) is regarded as a simple but important reaction among various C-F functionalizations, which features a mechanistic diversity as model reactions for C-F bond activations. Following Lentz and Braun's review (Angew Chem Int Ed 52, 3328-3348, 2013), we review transition-metal-mediated HDF reactions according to periodic table from group 3-12 metals.

引用

页码：143 / 196

页数：54

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