Multiphysics NMR correlation spectroscopy

被引:4
作者
Song, Yi-Qiao [1 ,2 ,3 ]
Souza, Andre [3 ,4 ]
Vembusubramanian, Muthusamy [3 ]
Tang, Yiqiao [3 ]
Fellah, Kamilla [3 ]
Feng, Ling [3 ]
Reeder, Stacy L. [3 ]
机构
[1] Massachusetts Gen Hosp, Dept Radiol, Athinoula A Martinos Ctr Biomed Imaging, Charlestown, MA 02129 USA
[2] Harvard Univ, John A Paulson Sch Engn & Appl Sci, Cambridge, MA 02138 USA
[3] Schlumberger Doll Res Ctr, 1 Hampshire St, Cambridge, MA 02139 USA
[4] Schlumberger Brazil Technol Integrat Ctr, Ave Republ Chile 330, BR-20031170 Rio De Janeiro, Brazil
关键词
Relaxation; Capillary drainage; Pore structure; Multi-dimensional experiments; MAGNETIC-RESONANCE; RELAXATION; SYSTEM; PORES; MODEL;
D O I
10.1016/j.jmr.2020.106887
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
One hallmark of modern nuclear magnetic resonance spectroscopy is the use of multi-dimensional correlation experiments typically with only spin Hamiltonians. However, spin systems may be affected by interactions and processes that are not controlled through the spin degree of freedom. This paper demonstrates a correlation spectroscopy between two different physical processes, one is NMR spin dynamics, and the other capillary drainage for the study of porous materials. We show that such a correlation experiment produces a joint capillary pressure (P-c) and NMR relaxation (T-2) correlation function, P-c-T-2 map that probes how pores are connected, an insight not available in conventional NMR or capillary experiments. (C) 2020 Elsevier Inc. All rights reserved.
引用
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页数:5
相关论文
共 33 条
[1]   Perspectives on NMR studies of CO2 adsorption [J].
Bernin, Diana ;
Hedin, Niklas .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2018, 33 :53-62
[2]  
Bottomley PA., 2016, HDB MAGNETIC RESONAN
[3]   Permeability from porosimetry measurements: Derivation for a tortuous and fractal tubular bundle [J].
Buiting, J. J. M. ;
Clerke, E. A. .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2013, 108 :267-278
[4]   EFFECTS OF DIFFUSION ON FREE PRECESSION IN NUCLEAR MAGNETIC RESONANCE EXPERIMENTS [J].
CARR, HY ;
PURCELL, EM .
PHYSICAL REVIEW, 1954, 94 (03) :630-638
[5]   Dispersion of T1 and T2 Nuclear Magnetic Resonance Relaxation in Crude Oils [J].
Chen, Joseph J. ;
Huerlimann, Martin ;
Paulsen, Jeffrey ;
Freed, Denise ;
Mandal, Soumyajit ;
Song, Yi-Qiao .
CHEMPHYSCHEM, 2014, 15 (13) :2676-2681
[6]   Ex Situ NMR Relaxometry of Metal-Organic Frameworks for Rapid Surface-Area Screening [J].
Chen, Joseph J. ;
Kong, Xueqian ;
Sumida, Kenji ;
Manumpil, Mary Anne ;
Long, Jeffrey R. ;
Reimer, Jeffrey A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (46) :12043-12046
[7]   Measurement of rock-core capillary pressure curves using a single-speed centrifuge and one-dimensional magnetic-resonance imaging [J].
Chen, Q ;
Balcom, BJ .
JOURNAL OF CHEMICAL PHYSICS, 2005, 122 (21)
[8]   What is the shape of pores in natural rocks? [J].
Chen, Q ;
Song, YQ .
JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (19) :8247-8250
[9]   High-resolution X-ray computed tomography in geosciences: A review of the current technology and applications [J].
Cnudde, V. ;
Boone, M. N. .
EARTH-SCIENCE REVIEWS, 2013, 123 :1-17
[10]  
Coates G.R., 1999, NMR logging, principles and interpretation