The prognostication of columnar mesophases - Synthesis and mesomorphism of some porphyrin derivatives

被引:0
|
作者
Olga, B
Zdanovich, SA
机构
[1] Ivanovo State Univ, Ivanovo 153000, Russia
[2] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia
关键词
porphyrin; mesomorphism; liquid crystals;
D O I
暂无
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The existence of columnar mesophases (CM) for a new series of the porphyrin derivatives is predicted. With this purpose, the computation of molecular parameters (K, K-c, K-s, K-p, M-m, M-r) is carried out for eighty five molecules, including materials with a small number of peripheral substitutes. For verification of the existence of CM in the series of materials examined, some of them are synthesized and their mesomorphism is investigated.
引用
收藏
页码:797 / 808
页数:12
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